质子诱导x射线辐射法测定金基体中铅和其他元素

D. Daniel, A. Bello, A. Abdurrahman, I. K. Jonathan
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摘要

最近,在凯比州及其周边地区,铅中毒正在成为一种流行病。从据信铅浓度高的矿区收集了5个样本。采用2.5MeV质子束诱导x射线发射(PIXE)技术对尼日利亚Kebbi州Maga、Danko Wasagu LG 5个地质样品进行了特征表征,测定了铅(Pb)和其他微量元素的浓度。样品在尼日利亚奥孙州Ile-Ife能源研究与发展中心进行辐照和分析。结果表明,铅在所有样品中均为商业矿床。同时还测定了Si、S、K、Ca、Ti、Cr、Fe、Cu、Zn、Rb、Sr、Zr、Ba、P、V、Mn、Cl、Ce、Ni。A、B、C、D、E样品的铅浓度分别为943ppm、445ppm、3279ppm、212𝟶ppmand 529ppm,均高于有儿童地区400ppm的世界卫生建议值。此外,元素Si和Fe的浓度似乎以商业数量沉积。这些价值意味着,尼日利亚凯比州Danko Wasagu LG Maga的矿工和周围社区面临着由于高浓度铅而导致的学习障碍、注意力缺陷障碍、行为问题、发育迟缓、听力问题、贫血、肾损伤、胃痛、智力迟钝、昏迷和死亡的风险。
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Determination of Lead and Other Elements in Gold Matrix Using Proton Induced X-Ray Emission At Maga, Danko Wasagu, Kebbi, Nigeria
Lead poisoning is becoming an epidemic in and around Kebbi State lately. Five samples were collected from mining Sites believed to have high lead concentration. Proton induced X-ray emission (PIXE) technique of 2.5MeV proton beam was used to characterize five geological samples collected from Maga, Danko Wasagu LG, Kebbi State, Nigeria to determined concentration of Lead (Pb) and other trace elements. Samples were irradiated and analyzed at Centre for Energy Research and Development, Ile-Ife, Osun State, Nigeria. The result obtained indicated that Pb is of commercial deposit in all the samples. Alongside, Si, S, K, Ca, Ti, Cr, Fe, Cu, Zn, Rb, Sr, Zr, Ba, P, V, Mn, Cl, Ce and Ni were determined. The result obtained for Pb concentration in samples A, B, C, D and E were 943ppm, 445ppm, 3279ppm, 212𝟶ppmand 529ppm respectively, which is above the world health recommendation of 400ppm for areas with children.Also element Si and Fe concentrations appear to be deposited in commercial quantities. These values imply that the miners and surrounding communities of Maga, Danko Wasagu LG, Kebbi State, Nigeria are at risk of learning disabilities, attention deficit disorders, behavioural problems, stunted growth, hearing problems, anaemia, kidney damage, stomach pain, mental retardation, coma, and death due to the high concentration of Pb.
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