掺Er3+离子的低声子能玻璃作为白光发射器

A. Saeed, W. Abu-raia, M. Farag
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引用次数: 6

摘要

白光发射器仍然需要不断开发和研究新材料。在这种情况下,采用传统的熔融/铸造技术制备了含有Er3+离子的低声子能量玻璃。利用x射线荧光(XRF)测量分析了合成材料的化学成分。x射线衍射(XRD)图谱有力地证实了所制备材料的非晶本质。密度和傅里叶变换红外光谱(FTIR)的行为表明,Er3+离子具有改性作用,并且在所研究的玻璃网络内形成了非桥接氧NBOs。所研究的玻璃具有低声子能量,范围在647 ~ 659 cm-1之间。根据Er3+离子注入所引起的结构变化,讨论了所得的热学、热力学、力学和光学性质。该玻璃具有高热稳定性、高热膨胀、高折射率等特点。随着Er3+离子含量的增加,合金的显微硬度VMH由3.78 GPa降至3.20 GPa。在近紫外NUV 380 nm激发波长下,有三个发射波段;可以观察到蓝色、绿色和红色。这些颜色的适当组合就可能产生白光。利用CIE 1931色度图和相关色温值确认冷白光发射。根据得到的结果,所研究的玻璃被指定为光子应用中的白光发射器。
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Er3+ ion doped low phonon energy glass as a white light emitter
White light emitters remain in the need of continual development and research for new materials. In this context, a low phonon energy glass containing Er3+ ions was prepared using the conventional melt/casting technique. The chemical compositions of the synthesized materials were analyzed using X-Ray Fluorescence (XRF) measurements. X-Ray Diffraction (XRD) pattern strongly affirms the non-crystalline essence of the produced materials. The behavior of both density and Fourier Transform Infrared (FTIR) spectroscopy denoted that the Er3+ ions have a modifier role and non-bridging oxygens NBOs were formed inside the studied glass network. The studied glasses have low phonon energy, ranging from 647 to 659 cm-1. The obtained results of the thermal, thermo-mechanical, mechanical, and optical properties were discussed in light of the structural changes brought about by inserting Er3+ ions inside the studied network. The present glasses have high thermal stability, high thermal expansion, and high refractive index. With the increase of Er3+ ion content, the Vickers microhardness VMH decreased from 3.78 GPa to 3.20 GPa. Under near ultraviolet NUV 380 nm excitation wavelength, three emission bands; blue, green, and red are observed. The white light is possible by a suitable combination of these colors. The cool white light emission was confirmed using CIE 1931 chromaticity diagram and correlated color temperature values. According to the obtained results, the studied glasses are nominated as a white light emitter in photonic applications.
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