自组装三元阵列中的多步光诱导电子转移过程——迈向高效有机太阳能电池的精确纳米制造

S. Mathew, M. Johnston
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引用次数: 0

摘要

构造了一种含锌卟啉、苝二亚胺和甲烷富勒烯的多色三元配合物。采用顺序斯特恩-沃尔默分析证明了三元配合物的形成,并通过多步光诱导电子转移研究了电荷分离态的能量学。
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Multistep photoinduced electron transfer processes in a self-assembled ternary array - Towards precise nanofabrication of efficient organic solar cells
A multichromophoric ternary complex containing a zinc porphyrin, perylene diimide and a methanofullerene was constructed. The use of a sequential Stern-Volmer analysis was employed to demonstrate the formation of the ternary complex and the energetics of a charge-separated state through a multistep photoinduced electron transfer was investigated.
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