溶液法制备聚对苯二甲酸乙酯/蒙脱土纳米复合薄膜

D. Aht-Ong, H. Benjapornthavee
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引用次数: 3

摘要

采用溶液法制备了聚对苯二甲酸乙酯(PET)/蒙脱土(MMT)纳米复合材料,以苯酚/四氯乙烷50/50为溶剂,在超声波的辅助下促进蒙脱土在PET溶液中的相容性和分散性。PET浓度为5%、7%和9% w/v。两种类型的MMT:纯MMT和有机粘土;以二甲基二十八烷基铵(2C18-MMT)为改性剂,分别以1、3、5、10个单位/小时的用量对MMT进行改性,制备纳米级复合材料。考察了PET溶液浓度、MMT类型(有机粘土和纯MMT)以及MMT含量对PET/MMT纳米复合材料物理、力学和光学性能的影响。
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Preparation of poly(ethylene terephthalate)/montmorillonite nanocomposites films by solution technique
Poly (ethylene terephthalate) (PET)/montmorillonite (MMT) nanocomposites were prepared by solution technique using 50/50 phenol/tetrachloroethane as a solvent, assisted with the ultrasonic power to promote the compatibility and dispersion of the montmorillonite in the PET solution. The PET concentrations were varied from 5, 7, and 9 %w/v. Two types of MMT: neat MMT and organoclay; MMT modified with dimethyl dioctadecyl ammonium (2C18-MMT) were used with various amount from 1, 3, 5 and 10 phr to produce nano-scale composites. The effects of PET solution concentration, MMT types (organoclay and neat MMT), and MMT content on the physical, mechanical, and optical properties of the PET/MMT nanocomposites were investigated.
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