支撑液膜处理放射性废物的选择与设计准则

S. Biswas, Sangita Pal, S. Roy, P. K. Tewari
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引用次数: 1

摘要

支撑液膜(SLM)是一种新兴的微量金属预富集技术。它有能力去污放射性核素,甚至从稀薄的二级污水。SLM可以被认为是过程强化的一部分,这意味着一个闭环操作。它减少了对空间的需求,并最大限度地减少了二次废水的产生和单位步骤的数量。适当选择分子设计标准有助于决定诸如选择性、相容性、渗透性等性能,这些性能归因于进料和所需的溶出剂特性,并且已经在印度Trombay铀金属厂产生的核电厂废物处理中应用了大量的努力。本文阐述了SLM的基本观点,通过实验验证对进料和剥离剂进行进一步处理的载体选择,以及结构方面的证据(来自FT-IR研究)。
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Selection and design criteria of supported liquid membrane for the treatment of rad-waste
Supported Liquid Membrane (SLM) is an emerging trace metal pre-concentration technique. It has the ability to decontaminate radionuclides even from lean secondary effluent. SLM can be considered as a part of process intensification, which implies a closed loop operation. It has reduced space requirement as well as minimised secondary effluent generation and the number of unit steps. Proper selection of molecular design criteria helps in deciding performances such as selectivity, compatibility, permeability, etc., that is attributed to both feed and desired strippant characteristics, and great effort has been applied for nuclear plant waste treatment generated in the uranium metal plant of Trombay, India. This paper articulates basic views of SLM, selection of carrier by experimental verification with respect to both feed and strippant for further processing, and structural aspects with evidences (from FT-IR studies).
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