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Nanosensors applied to water quality: developing a low-cost pH sensor for natural water, and application of other techniques 纳米传感器在水质中的应用:开发用于天然水的低成本pH传感器,以及其他技术的应用
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040124
P. Herrmann
A low-cost optical sensor built-in strip has been developed from a composite obtained with application of in-situ chemical polymerisation, using polyaniline in the emeraldine oxidation state, doped with HCl onto poly(ethylene terephthalate) (PET) film, used to measured the pH of water. The absorption of UV-Vis spectra was used to evaluate the optical response to pH change of natural water. The strip showed a reversible colour change upon variation of the pH. The pH range used to calibrate the optical sensor was from 2.0 to 12.0. These kinds of sensors show the potential to investigate the pH of natural waters, with application to limnological studies, as well as to investigate the influence of the ionic strength. This paper describes new techniques that can be used to conduct research with pesticides in water using electrochemistry and biosensors, and an electronic tongue with conductive polymers for global quality evaluation.
一种低成本的光学传感器内置条是由原位化学聚合获得的复合材料制成的,使用祖母绿氧化态的聚苯胺,在聚对苯二甲酸乙酯(PET)薄膜上掺杂HCl,用于测量水的pH值。利用紫外可见吸收光谱评价了天然水对pH变化的光学响应。随着pH值的变化,该条带显示可逆的颜色变化。用于校准光学传感器的pH值范围为2.0至12.0。这些类型的传感器显示出研究天然水的pH值的潜力,应用于湖泊学研究,以及研究离子强度的影响。本文介绍了利用电化学和生物传感器进行水中农药研究的新技术,以及用于全球质量评估的导电聚合物电子舌。
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引用次数: 3
The CEA/BARC collaboration on the use of nuclear reactors for desalination CEA/BARC在使用核反应堆进行海水淡化方面的合作
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040123
S. Dardour, P. K. Tewari
This paper presents the collaboration between the French Atomic Energy Commission (Commissariat a l'Energie Atomique, CEA) and the Indian Bhabha Atomic Research Centre (BARC) on the use of nuclear reactors for desalination. The joint RD and (b) extraction of valuable materials from the concentrated brine rejected by water plants. The results achieved during phase I of the collaboration include the development, implementation and partial validation of models describing the behaviour of multi-effect evaporators (MEE) equipped with a mechanical vapour compression device (MVC), the assessment of the influence of the feed water properties on the performance of the reverse osmosis (RO) process and the identification of methods and protocols for the extraction of valuable materials from brine reject. This effort will continue during phase II of the project with a particular emphasis on model extension, validation and application.
本文介绍了法国原子能委员会(commissaria l’energie Atomique, CEA)和印度巴巴原子研究中心(BARC)在使用核反应堆进行海水淡化方面的合作。联合研发和(b)从水厂排出的浓盐水中提取有价值的物质。在合作的第一阶段取得的成果包括开发、实施和部分验证模型,这些模型描述了配备机械蒸汽压缩装置(MVC)的多效蒸发器(MEE)的行为,评估了给水特性对反渗透(RO)过程性能的影响,并确定了从盐水废水中提取有价值物质的方法和协议。这项工作将在项目的第二阶段继续进行,特别强调模型的扩展、验证和应用。
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引用次数: 0
Challenges and approach to integrated water resource management 水资源综合管理的挑战和方法
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040122
P. K. Tewari
Water is the natural resource on which human life, food security and the health of ecosystems depend. The requirement for water is increasing rapidly owing to progressive increase in the demand for irrigation, rapid industrialisation, population growth and improving living standards. The existing water resources are diminishing due to (a) unequal distribution of rain leading to drought, (b) excessive exploitation of groundwater sources and (c) deterioration of water quality owing to the discharge of domestic and industrial effluents without adequate treatment. A large number of villages in India and several other parts of the world are known to be suffering from excess salinity, fluoride, iron, arsenic and microbial contaminations of ground water. There are areas that face perennial water shortage. Thus, the sustainable management of water is one of the key challenges that our society is facing today. This paper discusses different challenges and approaches to integrated water resource management.
水是人类生命、粮食安全和生态系统健康所依赖的自然资源。由于灌溉需求的逐步增加、快速工业化、人口增长和生活水平的提高,对水的需求正在迅速增加。现有的水资源正在减少,原因是:(a)雨水分配不均导致干旱;(b)地下水资源过度开采;(c)由于未经适当处理而排放家庭和工业污水而导致水质恶化。众所周知,印度和世界上其他几个地区的许多村庄的地下水受到过量的盐度、氟化物、铁、砷和微生物污染。有些地区长期面临缺水问题。因此,水的可持续管理是当今社会面临的主要挑战之一。本文讨论了水资源综合管理面临的不同挑战和途径。
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引用次数: 0
Sorption kinetic studies using metal chelate embedded polymers for recovery of heavy metals from desalination effluents 金属螯合物包埋聚合物对海水淡化废水中重金属的吸附动力学研究
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040127
T. Prasad, P. K. Tewari, D. Sathiyamoorthy
The heavy metals, such as uranium and vanadium, are some of the valuable metals in desalination effluents. Metal Chelate Embedded Polymers (MCEP) in leaflet form were prepared using the post-irradiation induced graft polymerisation technique, with different non-woven thermally bonded fibrous substrate materials. The novel sorbents, synthesised by using accelerator energy beams of 1.25 MeV and 2 MeV, were characterised for their radiation, chemical and mechanical characteristics. The novel sorbent was evaluated under different parametric conditions, in order to study the influence of grafting levels, initial concentration, dissolved solids and contact time. The standard isotherm and diffusion models were fitted to the experimental sorption data and model parameters were evaluated. The sorption characteristics of MCEP for recovery of heavy metals such as uranium and vanadium from desalination effluents were investigated.
重金属,如铀和钒,是海水淡化废水中的一些有价金属。采用辐照诱导接枝聚合技术,以不同的无纺布热粘合纤维为基体材料,制备了小叶状金属螯合物嵌入聚合物(MCEP)。利用1.25 MeV和2 MeV的加速器能量束合成的新型吸附剂,对其辐射、化学和机械特性进行了表征。在不同的参数条件下,研究了接枝水平、初始浓度、溶解固形物和接触时间对新型吸附剂性能的影响。对实验吸附数据拟合了标准等温线和扩散模型,并对模型参数进行了评价。研究了MCEP对海水淡化废水中重金属铀、钒的吸附特性。
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引用次数: 2
Innovation in radioactive wastewater-stream management. Part II: theoretical model and experimental verification 放射性废水流管理的创新。第二部分:理论模型和实验验证
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040125
A. Karameldin, N. M. A. El-Monem, L. Shouman, D. A. Fadel
The present work is the second part of the authors’ innovative method for radioactive wastewater-stream management, by volume reduction, by a mutual heating and humidification of a compressed dry air introduced through the wastewater. In this part, to determine the optimal operating conditions, a theoretical model describing volume reduction of the radioactive wastewater stream is achieved. A set of first-order simultaneous differential equations describing the bubble humidity, temperature, liquid temperature, and mass diffusion to the bubbles variations, are obtained through the mass and energy conservations. A set of coupled first-order differential equations are used to solve for the humidity ratio, water diffused to the air stream, water temperature and humid air stream temperature distributions through the bubbling column. These coupled differential equations are simultaneously solved numerically by a developed computer program using the fourth-order Runge–Kutta method. Therefore, the behaviour of the air bubble state variables with column height can be predicted and optimised. Moreover, the design curves of the volumetric reduction of the wastewater streams are obtained and assessed at the different operating conditions. An experimental set-up was constructed to verify the suggested model. Comprehensive comparison between suggested model results, recent experimental measurements and the results of previous works was carried out and assessed. A good agreement between experimental and theoretical model is obtained. A semi-empirical correlation is obtained together with design curve of bubbling column.
目前的工作是作者对放射性废水流管理的创新方法的第二部分,通过减少体积,通过废水引入的压缩干燥空气的相互加热和加湿。在这一部分中,为了确定最佳操作条件,实现了描述放射性废水流体积减小的理论模型。通过质量守恒和能量守恒,得到了描述气泡湿度、温度、液体温度和质量扩散随气泡变化的一阶联立微分方程。采用一阶耦合微分方程求解了鼓泡塔内的湿度比、扩散到气流中的水、水温和湿气流温度的分布。利用开发的四阶龙格-库塔法对这些耦合微分方程进行了数值求解。因此,可以预测和优化气泡状态变量随柱高的变化规律。此外,还得到了不同运行条件下废水流体积减小的设计曲线,并对其进行了评价。建立了一个实验装置来验证所提出的模型。对建议的模型结果、最近的实验测量结果和以前的工作结果进行了全面的比较和评估。实验结果与理论模型吻合较好。并与鼓泡塔设计曲线进行了半经验关联。
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引用次数: 0
Energy cost for desalination evaporation versus reverse osmosis 淡化蒸发与反渗透的能源成本
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040128
M. Rognoni, M. Ramaswamy, J. Paden
The selection of the appropriate desalination technology between evaporation and reverse osmosis is grounded on several factors, including investment cost, maintenance cost, degree of availability, heaviness of the duty, and the required purity of the desalinated water. The main factor is often the running cost of the plant, and specifically the cost of the consumed energy. This paper intends to demonstrate that the real value of the steam bleed is a function of several factors, mainly of the cost of fuel and of its importance in the total cost of the energy. The lower the cost of fuel, the less is the value of the steam bleed up to the extent that the cost of the energy consumption can be lower for evaporation than for reverse osmosis.
在蒸发和反渗透之间选择合适的海水淡化技术取决于几个因素,包括投资成本、维护成本、可用性程度、任务的轻重和淡化水所需的纯度。主要因素通常是工厂的运行成本,特别是消耗能源的成本。本文的目的是证明蒸汽排放的实际值是几个因素的函数,主要是燃料成本及其在总能源成本中的重要性。燃料成本越低,蒸汽排放的价值就越小,以至于蒸发的能耗成本比反渗透的低。
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引用次数: 4
Thin film composite type positively charged nanofiltration membrane for separation of aqueous streams and nuclear effluents 膜复合型正电纳滤膜用于分离水流和核废水
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040129
T. K. Dey, R. C. Bindal, S. Prabhakar, P. K. Tewari
Thin film composite type positively charged nanofiltration membrane developed by in situ polymerisation of functionalised polyethyleneimine and acid chloride has been used in various aqueous stream separations. The membrane contained fixed quaternary ammonium moieties which contributed to its positive charge. The membrane was tested for its performance in single solute feed systems containing salts of various combinations of univalent and bivalent ions (NaCl, Na 2 SO 4 , CaCl 2 and MgSO 4 ) in test cells as well as spiral module where it gave differential separation profile for these solutes with high rejection for CaCl 2 and low rejection for Na 2 SO 4 . The 2512 spiral module of the membrane was further used for separation of a simulated effluent solution containing uranyl nitrate, which is a common effluent generated in the nuclear industry. The membrane gave a high separation for uranyl nitrate and low separation for ammonium nitrate indicating that both the solutes can be fractionated by the membrane...
由功能化聚乙烯亚胺和氯化酸原位聚合而成的薄膜复合型正电纳滤膜已用于各种水相分离。该膜含有固定的季铵基团,这有助于其带正电荷。在测试单元中测试了该膜在含有各种一价和二价离子(NaCl, na2so4, cacl2和mgso4)组合的单一溶质进料系统中的性能,并在螺旋模块中对这些溶质进行了不同的分离,对cacl2的截除率高,对na2so4的截除率低。该膜的2512螺旋模块进一步用于分离含有硝酸铀酰的模拟废水,硝酸铀酰是核工业中产生的常见废水。该膜对硝酸铀酰的分离率较高,对硝酸铵的分离率较低。
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引用次数: 0
Selection and design criteria of supported liquid membrane for the treatment of rad-waste 支撑液膜处理放射性废物的选择与设计准则
Pub Date : 2011-05-19 DOI: 10.1504/IJND.2011.040126
S. Biswas, Sangita Pal, S. Roy, P. K. Tewari
Supported Liquid Membrane (SLM) is an emerging trace metal pre-concentration technique. It has the ability to decontaminate radionuclides even from lean secondary effluent. SLM can be considered as a part of process intensification, which implies a closed loop operation. It has reduced space requirement as well as minimised secondary effluent generation and the number of unit steps. Proper selection of molecular design criteria helps in deciding performances such as selectivity, compatibility, permeability, etc., that is attributed to both feed and desired strippant characteristics, and great effort has been applied for nuclear plant waste treatment generated in the uranium metal plant of Trombay, India. This paper articulates basic views of SLM, selection of carrier by experimental verification with respect to both feed and strippant for further processing, and structural aspects with evidences (from FT-IR studies).
支撑液膜(SLM)是一种新兴的微量金属预富集技术。它有能力去污放射性核素,甚至从稀薄的二级污水。SLM可以被认为是过程强化的一部分,这意味着一个闭环操作。它减少了对空间的需求,并最大限度地减少了二次废水的产生和单位步骤的数量。适当选择分子设计标准有助于决定诸如选择性、相容性、渗透性等性能,这些性能归因于进料和所需的溶出剂特性,并且已经在印度Trombay铀金属厂产生的核电厂废物处理中应用了大量的努力。本文阐述了SLM的基本观点,通过实验验证对进料和剥离剂进行进一步处理的载体选择,以及结构方面的证据(来自FT-IR研究)。
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引用次数: 1
Preparation and surface modification of hollow fibre membranes for drinking water disinfection and water reclamation 饮用水消毒及水回收用中空纤维膜的制备及表面改性
Pub Date : 2010-09-13 DOI: 10.1504/IJND.2010.035173
P. Ray, Puyam S. Singh, K. Parashuram, S. Maurya, J. Trivedi, C. V. Devmurari, N. N. Rao, S. Waghmare, A. Reddy
Polysulphone hollow fibres were spun according to phase inversion process under different conditions by extrusion of dimethylformamide solution of the polymer through double orifice spinneret using water or water-DMF mixture as gelation medium. The membrane surface was modified by in situ interfacial polymerisation of m-phenylenediamine with trimesoyl chloride. The nominal molecular weight cut-off (MWCO) values of the virgin fibres were 44,000?94,000 g/mol, which were decreased to 10,000?14,000 g/mol upon surface modification. The contact angle of the virgin fibres was about 87° and was decreased to about 65° by surface modification. HF modules exhibited pure water fluxes of 40?70 litre/m²h at 25 psi, and 4?5 log reduction for microorganisms like cocci, E. coli and bacillus when tested with water containing 1010 cfu/ml of bacteria. Fibres were tested for the treatment of municipal sewage water for a period of 20 days and constant rejection-flux profile was observed throughout the period.
以水或水- dmf混合物为胶凝介质,通过双孔喷丝器挤出聚合物的二甲基甲酰胺溶液,在不同条件下按相转化工艺纺制聚砜中空纤维。采用间苯二胺与三甲基氯原位界面聚合的方法对膜表面进行了改性。原始纤维的标称分子量截止值(MWCO)为44,000?94,000 g/mol,减少到10,000?表面改性后14000 g/mol。原始纤维的接触角约为87°,经表面改性后降至65°左右。HF模块的纯水通量为40?70l /m²h,在25psi, 4?在含有1010cfu /ml细菌的水中测试时,对球菌、大肠杆菌和芽孢杆菌等微生物的对数降低5。对纤维处理城市污水进行了为期20天的测试,并在整个期间观察到恒定的垃圾通量分布。
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引用次数: 3
Operating Experience of Desalination Unit Coupled to Primary Coolant System of Cirus 海水淡化机组与Cirus一次冷却系统耦合的运行经验
Pub Date : 2010-09-13 DOI: 10.5772/21313
Rakesh Ranjan, Surinder Kumar, D. Mathur, N. Ramesh, R. Sharma
CIRUS is a 40 MWth, light water cooled research reactor located at Trombay, Mumbai. The reactor was shut down in 1997 for refurbishment and restarted in 2003. At Bhabha Atomic Research Centre R&D activities on desalination have led to development of desalination technologies based on Multistage Flash (MSF) evaporation, Reverse Osmosis (RO) and Low Temperature Evaporation (LTE). Based on LTE, a 30 cubic metre per day pilot plant was designed and integrated to CIRUS during refurbishing outage as part of demonstration of utilisation of waste heat of nuclear reactors for seawater desalination. The work involved design, installation and commissioning of set-up to transfer heat from primary coolant of CIRUS to desalination unit through an intermediate Demineralised (DM) water circuit. The unit has been operated at its rated capacity and product water has been used to augment the demineralised water inventory of the primary coolant system. This paper highlights the experience gained during installation, commissioning and operation of the desalination unit.
CIRUS是一个40兆瓦的轻水冷却研究堆,位于孟买的Trombay。该反应堆于1997年关闭进行整修,并于2003年重新启动。在Bhabha原子研究中心,海水淡化的研发活动导致了基于多级闪蒸(MSF)蒸发、反渗透(RO)和低温蒸发(LTE)的海水淡化技术的发展。基于LTE, CIRUS设计了一个30立方米/日的中试工厂,并在翻新停运期间将其整合到CIRUS,作为利用核反应堆余热进行海水淡化的示范项目之一。这项工作包括设计、安装和调试装置,通过中间脱矿(DM)水路将CIRUS主冷却剂的热量传递给脱盐装置。该机组已在其额定容量下运行,产品水已用于增加一次冷却剂系统的脱盐水库存。本文着重介绍了海水淡化装置在安装、调试和运行过程中所取得的经验。
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引用次数: 2
期刊
International Journal of Nuclear Desalination
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