强光-物质耦合中的新效应

M. Ruggenthaler
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引用次数: 0

摘要

在过去的十年中,大量开创性的实验结果表明,分子和固体的性质和动力学可以通过与光子环境(例如光学腔)的电磁场强耦合来改变和控制。为了详细了解这种变化,有必要使用第一原理方法来研究强光-物质相互作用。在这次演讲中,我将讨论这种从头计算方法的基本设置,库仑规范中的Pauli-Fierz量子场论,介绍量子电动力学密度泛函数理论作为一种有效和准确的模拟技术,并强调可以获得的新效应。除此之外,我还演示了如何修改传导和吸收特性,集体强耦合如何诱导强局部修改以及连续体中的束缚态如何出现。
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Novel effects in strong light-matter coupling
In the last decade a host of seminal experimental results have demonstrated that properties and dynamics of molecules and solids can be modified and controlled by coupling strongly to the electromagentic field of a photonic environment, e.g. an optical cavity. For a detailed understanding of such changes it becomes necessary to use first-principles approaches to strong light-matter interactions. In this talk I will discuss the fundamental setting for such ab-initio methods, the Pauli-Fierz quantum field theory in Coulomb gauge, introduce quantum-electrodynamical density-functional theory as an efficient and accurate simulation technique and highlight novel effects that become accessible. Among others I demonstrate how conduction and absorption properties are modified, how collective strong coupling can induce strong local modifications and how bound states in the continuum appear.
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