Maimunawaro Maimunawaro, S. K. Rahman, Chairul Irawan
{"title":"利用有机废物中的腐殖酸作为铅合成废弃物(Pb)的补充","authors":"Maimunawaro Maimunawaro, S. K. Rahman, Chairul Irawan","doi":"10.5614/JTKI.2020.19.1.5","DOIUrl":null,"url":null,"abstract":"Abstrak. Industri pelapisan logam disamping memiliki konstribusi bagi perekonomian Indonesia, namun dalam prosesnya menghasilkan limbah cair yang memberikan dampak negatif bagi lingkungan karena mengandung logam berat. Salah satu teknik pengolahan limbah cair yaitu adsorpsi menggunakan asam humat dari ekstraksi sampah organik yang dijadikan adsorben. Kelebihan proses adsorpsi ini ialah pengerjaannya mudah, biaya relatif murah, relatif aman dari kontaminasi zat-zat kimia, serta tidak memberikan polusi berarti bagi lingkungan. Ekstraksi asam humat dari sampah organik berlangsung secara bertahap menggunakan proses ekstraksi dengan 1 L NaOH dengan variasi pelarut 0,1 N dan 0,5 N. Karakterisasi sebelum dan sesudah ekstraksi menggunakan Fourier-transform infrared spectroscopy (FTIR), X-Ray Diffraction (XRD), dan Scanning Electron Microscope (SEM), masing-masing untuk mengetahui gugus fungsional, struktur kristal, serta struktur morfologi pada asam humat. Proses adsorpsi menggunakan asam humat sebagai adsorben dilakukan secara batch dengan massa adsorben 1 g/L, kecepatan pengadukan 150 rpm, temperatur ruang dan pH 6,7–7,0 selama 1 jam. Analisa setelah adsorpsi menggunakan metode Atomic Absorption Spectrofotometer (AAS) untuk uji kadar timbal (Pb (II)). Hasil adsorpsi timbal (Pb) pada kedua variasi pelarut adsorben dengan pH awal 6,7–7,0 memiliki keefektifan masing-masing mencapai hampir 98%. Kata kunci:adsorben, asam humat, ekstraksi, sampah organik. Abstract. Removal of Lead (II) of Synthetic Wastewater Using Humic Acid Extracted from Organic Waste As Adsorbent.Metal plating Industry mining productions contribute to the growth of the Indonesian economy, but during the processes usually create a negative environmental impact such as heavy metals. The adsorption method is one of various methods for wastewater treatment. The humic acid as adsorbent in the adsorption method had been extracted from organic waste. The advantages of this method are simple, cheap and secure from chemical contaminant. The extraction of humic acid from organic waste takes place gradually using 1 L NaOH with a variety of solvents of 0.1 N and 0.5 N.The humic acid before and after treatment was characterized using Fourier-transform infrared spectroscopy (FTIR) X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM). The adsorption process was carried out in batch experiment with mass adsorbent of 1 g/L, stirring speed of 150 rpm, room temperatur, pH around 6.7–7.0 for 1 hour. The result showed by Atomic Absorption Spectroscopy (AAS) analysis characterize that adsorption lead (II) in several adsorbent concentrations at pH 6.7–7.07 has effectiveness 98%. Keywords: adsorbents, extraction, humic acid, organic waste. ","PeriodicalId":138501,"journal":{"name":"Jurnal Teknik Kimia Indonesia","volume":"9 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2021-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Pemanfaatan Asam Humat Dari Sampah Organik Sebagai Adsorben Pada Limbah Cair Sintesis Timbal (Pb)\",\"authors\":\"Maimunawaro Maimunawaro, S. K. Rahman, Chairul Irawan\",\"doi\":\"10.5614/JTKI.2020.19.1.5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstrak. Industri pelapisan logam disamping memiliki konstribusi bagi perekonomian Indonesia, namun dalam prosesnya menghasilkan limbah cair yang memberikan dampak negatif bagi lingkungan karena mengandung logam berat. Salah satu teknik pengolahan limbah cair yaitu adsorpsi menggunakan asam humat dari ekstraksi sampah organik yang dijadikan adsorben. Kelebihan proses adsorpsi ini ialah pengerjaannya mudah, biaya relatif murah, relatif aman dari kontaminasi zat-zat kimia, serta tidak memberikan polusi berarti bagi lingkungan. Ekstraksi asam humat dari sampah organik berlangsung secara bertahap menggunakan proses ekstraksi dengan 1 L NaOH dengan variasi pelarut 0,1 N dan 0,5 N. Karakterisasi sebelum dan sesudah ekstraksi menggunakan Fourier-transform infrared spectroscopy (FTIR), X-Ray Diffraction (XRD), dan Scanning Electron Microscope (SEM), masing-masing untuk mengetahui gugus fungsional, struktur kristal, serta struktur morfologi pada asam humat. Proses adsorpsi menggunakan asam humat sebagai adsorben dilakukan secara batch dengan massa adsorben 1 g/L, kecepatan pengadukan 150 rpm, temperatur ruang dan pH 6,7–7,0 selama 1 jam. Analisa setelah adsorpsi menggunakan metode Atomic Absorption Spectrofotometer (AAS) untuk uji kadar timbal (Pb (II)). Hasil adsorpsi timbal (Pb) pada kedua variasi pelarut adsorben dengan pH awal 6,7–7,0 memiliki keefektifan masing-masing mencapai hampir 98%. Kata kunci:adsorben, asam humat, ekstraksi, sampah organik. Abstract. Removal of Lead (II) of Synthetic Wastewater Using Humic Acid Extracted from Organic Waste As Adsorbent.Metal plating Industry mining productions contribute to the growth of the Indonesian economy, but during the processes usually create a negative environmental impact such as heavy metals. The adsorption method is one of various methods for wastewater treatment. The humic acid as adsorbent in the adsorption method had been extracted from organic waste. The advantages of this method are simple, cheap and secure from chemical contaminant. The extraction of humic acid from organic waste takes place gradually using 1 L NaOH with a variety of solvents of 0.1 N and 0.5 N.The humic acid before and after treatment was characterized using Fourier-transform infrared spectroscopy (FTIR) X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM). The adsorption process was carried out in batch experiment with mass adsorbent of 1 g/L, stirring speed of 150 rpm, room temperatur, pH around 6.7–7.0 for 1 hour. The result showed by Atomic Absorption Spectroscopy (AAS) analysis characterize that adsorption lead (II) in several adsorbent concentrations at pH 6.7–7.07 has effectiveness 98%. 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引用次数: 1
摘要
抽象。除了对印尼经济做出贡献外,金属涂料行业还在生产液体废物,对环境产生负面影响,因为它含有重金属。一种处理废水的方法是吸收从有机废物中提取的腐蚀性处理技术。吸收过程的优势在于,它们的工作成本相对较低,相对安全,不受化学污染,而且对环境没有任何意义。泥土的有机垃圾进行开采逐渐运用溶剂提取1 L NaOH与变化过程前后的0.1 N和0.5 N .描述提取使用Fourier-transform红外线spectroscopy (FTIR), x光Diffraction (XRD)、扫描电子科学展览功能(SEM),每个人都要知道星团,晶体结构,以及泥土上的形态结构。吸附过程使用humat酸作为adsorben进行,与质量为1 g/L的adsorben 1 /L、搅拌速度150转/分,空间温度和pH 6.7 - 7.0持续一小时。在沉降物使用原子吸收光谱仪进行铅测量后进行分析。铅适应介质与pH值为6.7 - 7.0的pH值相匹配的pH值分别为98%。关键词:邻苯二甲酸、萃取物、有机废物。抽象。去除线索(II)水的合成废物使用Humic Acid从有机废物As Adsorbent。金属塑料加工产品倾向于印尼经济的增长,但在加工过程中,它通常创造出一种像重金属金属一样负环境冲击。替代方法是wastewater治疗的各种方法之一。一种普遍存在的治疗方法从有机废物中提取出来。这种方法的优势是对化学接触者的简单、廉价和安全。从有机废物中提取的humic acid使用1个N和0.1 N. 5 N. humic acid之前和之后都是x射线显微扫描显微镜的特征。处理程序被引入了一种与1 g/L的质量合并,以150转的速度stirring speed,室温,pH值在6.7 - 7.0的一小时内。结果由原子吸收光谱仪(AAS)分析受损导引物(II)在pH 6.7 - 7 - 07中具有98%的效力。建议:吸收、提取、humic acid、有机废物。
Pemanfaatan Asam Humat Dari Sampah Organik Sebagai Adsorben Pada Limbah Cair Sintesis Timbal (Pb)
Abstrak. Industri pelapisan logam disamping memiliki konstribusi bagi perekonomian Indonesia, namun dalam prosesnya menghasilkan limbah cair yang memberikan dampak negatif bagi lingkungan karena mengandung logam berat. Salah satu teknik pengolahan limbah cair yaitu adsorpsi menggunakan asam humat dari ekstraksi sampah organik yang dijadikan adsorben. Kelebihan proses adsorpsi ini ialah pengerjaannya mudah, biaya relatif murah, relatif aman dari kontaminasi zat-zat kimia, serta tidak memberikan polusi berarti bagi lingkungan. Ekstraksi asam humat dari sampah organik berlangsung secara bertahap menggunakan proses ekstraksi dengan 1 L NaOH dengan variasi pelarut 0,1 N dan 0,5 N. Karakterisasi sebelum dan sesudah ekstraksi menggunakan Fourier-transform infrared spectroscopy (FTIR), X-Ray Diffraction (XRD), dan Scanning Electron Microscope (SEM), masing-masing untuk mengetahui gugus fungsional, struktur kristal, serta struktur morfologi pada asam humat. Proses adsorpsi menggunakan asam humat sebagai adsorben dilakukan secara batch dengan massa adsorben 1 g/L, kecepatan pengadukan 150 rpm, temperatur ruang dan pH 6,7–7,0 selama 1 jam. Analisa setelah adsorpsi menggunakan metode Atomic Absorption Spectrofotometer (AAS) untuk uji kadar timbal (Pb (II)). Hasil adsorpsi timbal (Pb) pada kedua variasi pelarut adsorben dengan pH awal 6,7–7,0 memiliki keefektifan masing-masing mencapai hampir 98%. Kata kunci:adsorben, asam humat, ekstraksi, sampah organik. Abstract. Removal of Lead (II) of Synthetic Wastewater Using Humic Acid Extracted from Organic Waste As Adsorbent.Metal plating Industry mining productions contribute to the growth of the Indonesian economy, but during the processes usually create a negative environmental impact such as heavy metals. The adsorption method is one of various methods for wastewater treatment. The humic acid as adsorbent in the adsorption method had been extracted from organic waste. The advantages of this method are simple, cheap and secure from chemical contaminant. The extraction of humic acid from organic waste takes place gradually using 1 L NaOH with a variety of solvents of 0.1 N and 0.5 N.The humic acid before and after treatment was characterized using Fourier-transform infrared spectroscopy (FTIR) X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM). The adsorption process was carried out in batch experiment with mass adsorbent of 1 g/L, stirring speed of 150 rpm, room temperatur, pH around 6.7–7.0 for 1 hour. The result showed by Atomic Absorption Spectroscopy (AAS) analysis characterize that adsorption lead (II) in several adsorbent concentrations at pH 6.7–7.07 has effectiveness 98%. Keywords: adsorbents, extraction, humic acid, organic waste.