工艺参数对煤焦油馏分产品的影响

A. Gupta, S. Sen, Ritesh Kumar, R. Ramna, S. Kumari, S. Dhakate
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摘要

煤焦油沥青根据其性质大致分为两种:铝工业用粘结沥青和石墨工业用低于0.5% QI(喹啉不溶物)的浸渍沥青。为了通过煤焦油的下游加工实现价值最大化,建议探索通过一级分馏将不同钢铁厂的不同质量的煤焦油转化为不同品种的煤焦油沥青(粘结剂以及铝和石墨工业的零QI浸渍)的可行性。在本研究中,收集了四种质量的煤焦油样品,其中三种来自工厂1 (TP-1、TP-2和TP-3),另一种来自工厂2 (TP-4),并将其送到实验室进行必要的评估、转化和随后的表征研究。从煤焦油(TP-1, TP-2和TP-3)中提取零QI浸渍沥青也可以采用溶剂萃取或沉淀法,但可能不具有成本效益。根据粘合剂和浸渍等级沥青的要求规格,通过协作工作优化了真空蒸馏过程中的工艺参数。在煤焦油样品转化为煤焦油沥青的过程中,QI含量与蒸馏温度、真空度和浸泡时间有关。
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Effect of Process Parameter on Coal Tar Distillate Products
Coal tar pitch is broadly classified into two kinds based on their properties: Binder Pitch for aluminum and Graphite Industry Impregnated Pitch with less than 0.5% QI (Quinoline Insoluble) used in the graphite industry. To maximize value realization through downstream processing of coal tar, proposal was made to explore the feasibility of conversion of different qualities of coal tars from different steel plants to coal tar pitch (CTP) of different varieties (binder as well as zero QI impregnated for both Al & graphite industries), through first level of fractional distillation. In this study, four qualities of coal tar samples three from plant 1 (TP-1, TP-2, and TP-3) and one from plant 2 (TP-4) were collected and sent to laboratory for necessary evaluation, conversion and subsequent characterization studies. Zero QI impregnated pitch from coal tar (TP-1, TP-2, and TP-3) can also be made using solvent extraction or sedimentation process, which may not be cost-effective. Depending on the required specifications for binder & impregnated grade pitches, process parameters during vacuum distillation, were optimized through this collaborative work. On conversion of coal tar sample into coal tar pitches, QI content depends on distillation temperature, vacuum and soaking time.
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