喀麦隆西部Meka'a粘土材料的矿物学和理化性质及其供人食用的初步研究

S. A. D. Ninla, A. Wouatong, S. T. Kouonang, B. Yerima, D. Njopwouo
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引用次数: 3

摘要

Meka'a地区新土食粘土矿床的发现,促进了当地市场上土食粘土材料新品种的出现。由于食土的积极或消极影响取决于所摄入的粘土的物理化学、矿物学和地球化学性质,因此有必要对这些粘土材料进行矿物学和物理化学表征,以确定它们对健康的影响。X射线衍射(XRD)、X射线荧光(XRF)、粒径分布、pH和阳离子交换容量(CEC)是对这些材料进行的主要分析。结果表明,麦卡亚粘土物质风化程度极高,可能是火成岩流风化的结果。根据其颜色、矿物学和物理化学特征,确定了这种粘土的两种主要种类(黄色和红色)。对这两类材料样品的分析表明,麦卡黏土材料主要由高岭石(64-87%)和针铁矿(6-25%)组成。这两种矿物对这些材料的性质影响很大。在这种粘土矿物组合中,高岭石的丰富可能有利于保护肠道,因为摄入了高粘土含量的土壤。这些粘土具有较低的CEC,不会引起消化道阳离子缺乏。它们的酸性pH值使它们适合用作缓解恶心和抑制与怀孕有关的唾液分泌的药物。食用麦卡黏土不会对牙釉质或胃肠道造成损伤,且富含锌,对食土个体有益。然而,考虑到氢氧化铁含量低,而且粘土中只有一部分铁可以在消化道中释放出来,因此Meka 'a粘土中补充铁的可能性可能很低。
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Mineralogical and Physico-Chemical Characterization of Clayey Materials of Meka'a (West Cameroon) Preliminary Step for Their Utilization for Human Ingestion
Discovery of new geophagic clayey deposit in the locality of Meka'a contributed to the apparition of new species of geophagic clay materials in the local market. Due to the fact that positive or negative effects of geophagia are conditioned by physico-chemical, mineralogical and geochemical properties of the clay soil ingested, it is therefore necessary to mineralogically and physico-chemically characterize these clayey materials in order to ascertain their health implications. X ray diffractometry (XRD), X ray fluorescence (XRF), particles size distribution, pH and cation exchance capacity (CEC) are the main analyses carried out with these materials. The results show that the clayey materials of Meka’a are extremely weathered and maybe as a result of the weathering of ignimbritic flows. Two main species (yellow and red) of this clay soil are identified on the basis of their colour, mineralogy and physico-chemical characteristic. Analysis of samples of these two types of materials shows that Meka’a clayey materials are mainly made up of kaolinite (64-87%) and goethite (6-25%). These two minerals greatly influence the properties of these materials. Abundance of kaolinite in this clayey mineral assemblage could be of benefit in the protection of gastro intestinal tract resulting from ingestion of soils with high clay content. These clayey soils have a lower CEC and cannot cause cations deficiency in the digestive tract. Their acidic pH makes them suitable for use as remedy for relief of nausea and to curb salivation associated with pregnancy. No dental enamel or gastro-intestinal tract damage was to be feared when ingesting Meka’a clayey soils and their great abundance in Zn could be of benefit to geophagic individuals. However, possibility of Fe supplementation of the clayey soils of Meka’a may be very low considering low ferric hydroxide content and the fact that only a part of Fe present in the clayey soil can be released in the digestive tract.
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