罗马尼亚食品工业废水的早期修复:改善乳制品工业废水质量的案例研究

F. Radu, S. Popescu, A. Cozma, A. Rinovetz, B. Radoi
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摘要

本研究的目的是展示在可持续发展的挑战背景下,不同的废水处理技术在乳制品行业中所发挥的作用:水资源短缺和水资源保护,人口的不断增长和集中系统中废水处理的成本,越来越多的约束和更严格的环境保护法规。从这个意义上说,确定了属于8家工厂的污水处理厂的效率。研究工厂根据污水处理技术的类型分为三组:第一组只使用预处理阶段;第二阶段采用机械化学和生物处理阶段,产沼气;第三组具有与反渗透模块耦合的好氧生物处理。在6个月期间(2022年3月至8月),每周从每个污水处理厂的进水和出水中采集水样。根据国家规定,对废水和处理后的水进行了8项水质参数分析。结果表明,所有废水样品的化学耗氧量(COD)、5 d生化耗氧量(BOD5)、总悬浮物(TSS)、总磷(PTotal)、总氮(NTotal)和铵态氮(铵态氮)均远远超过国家污水质量标准规定的允许范围。相反,pH值和氯化物含量在可接受的范围内。采用机械和生物法处理废水,COD、BOD5和TSS浓度分别降低95%以上,PTotal降低85%以上。反渗透模块对氨氮的去除效率可达95%以上。由于现场实施了这些技术来处理乳制品行业的废水,废水的质量指标值符合有关将处理后的水排放到自然容器或城市污水管网而不影响环境的规定。
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EARLY REMEDIATION OF WASTEWATERS FROM ROMANIAN FOOD INDUSTRY: A CASE STUDY OF IMPROVING THE QUALITY OF DAIRY INDUSTRY WASTEWATER
The purpose of this study was to demonstrate the role played by different wastewater treatment technologies in the dairy industry in the context of the challenges of sustainable development: water scarcity and conservation of water resources, the constant growth of the population and the costs of wastewater treatment in centralized systems, increasing constraints and stricter environmental protection regulations. In this sense, the efficiency of wastewater treatment plants belonging to a number of 8 factories was determined. The studied factories were divided into three groups according to the type of wastewater treatment technology, namely: the first group uses only the pretreatment stage; the second uses the mechanical-chemical and biological treatment stages with biogas production; the third group has an aerobic biological treatment coupled with a reverse osmosis module. Water samples were taken weekly from the influent and effluent of each wastewater treatment plant for 6 months (March-August 2022). A number of 8 quality parameters were analyzed for both waste water and treated water, in accordance with the national regulations. The results highlighted the fact that the values of chemical oxygen consumption (COD), five-days biochemical oxygen consumption (BOD5), total suspended solids (TSS), phosphorus (PTotal), respectively total nitrogen (NTotal), and ammonium nitrogen for all wastewater samples far exceeded the limits of admissibility provided by the national wastewater quality standards. Instead, the pH values and the chloride content were within acceptable limits. The apply of mechanical and biological wastewater treatments determined the decrease of COD, BOD5 and TSS concentrations by more than 95%, respectively by more than 85% in the case of PTotal. The efficiency of the reverse osmosis module was over 95% in the case of ammonium nitrogen elimination. As a result of the onsite implementation of these technologies for the treatment of wastewater from the dairy industry, the values of the quality indicators of the effluents were in accordance with the regulations regarding the discharge of treated water into natural receivers or into the urban sewage network without affecting the environment.
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