薄水铝石纳米叶结构对多孔α-Al2O3陶瓷的改性

Е. I. Senkina, А. S. Buyakov, А. S. Lozhkomoev
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摘要

对多孔陶瓷材料进行改性,使其功能特性的改善成为可能。在这项工作中,我们证明了用电爆炸Al/AlN纳米颗粒修饰大孔Al2O3陶瓷的薄水铝石纳米片结构的可能性。为此,将纳米颗粒悬浮液浸渍在多孔陶瓷中,然后将固定在多孔陶瓷体积中的纳米颗粒在60℃下进行水解和氧化反应。反应的结果是在陶瓷表面形成细粒薄水铝石纳米片结构。这使得样品的比表面积大大增加到25.9 m2/g成为可能。显著改善了宏观简单Al2O3陶瓷对伊红染料的吸附特性。在保护过程中,以0.15 cm/s的线性流速可吸附高达2.9 mg/g的染料。
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Modification of porous α-Al2O3 ceramics by boehmite nanoleaf structures
Modification of porous ceramic materials makes it possible to improve their functional characteristics. In this work, we demonstrate the possibility of modifying macroporous Al2O3 ceramics with boehmite nanosheet structures using electroexplosive Al/AlN nanoparticles. To do this, the porous ceramic was impregnated with a suspension of nanoparticles in ethanol, after which the reaction of hydrolysis and oxidation of the nanoparticles fixed in the volume of the porous ceramic was carried out at 60 °C. As a result of the reaction, nanosheet structures of fine-grained boehmite were formed on the ceramic surface. This made it possible to substantially increase the specific surface area of the sample to 25.9 m2/g. and significantly improve the sorption characteristics of macro-simple Al2O3 ceramics in relation to the eosin dye. During the protective action, it was possible to adsorb up to 2.9 mg/g of the dye at a linear flow rate of 0.15 cm/s.
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