纳米结构有机硅发光基团是一种新型的光下转换纳米材料

S. Ponomarenko, N. Surin, O. Borshchev, M. Skorotetcky, A. Muzafarov
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引用次数: 13

摘要

纳米结构有机硅发光团(NOLs)是一种支链分子结构,具有两种类型的共价键,通过硅原子有机发光团之间具有有效的Förster能量传递。它们结合了有机发光团和无机量子点的最佳特性:高吸收截面、优异的光致发光量子产率、快的发光衰减时间、良好的可加工性和低毒性。有机发光团的明智选择使我们能够设计和合成一个nol库,从紫外区吸收到可见光区,并在390到650 nm的所需波长范围内发射。它们可以在塑料闪烁体和其他应用中用作独特的波长移位器。
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Nanostructured organosilicon luminophores as a new concept of nanomaterials for highly efficient down-conversion of light
Nanostructured organosilicon luminophores (NOLs) are branched molecular structures having two types of covalently bonded via silicon atoms organic luminophores with efficient Förster energy transfer between them. They combine the best properties of organic luminophores and inorganic quantum dots: high absorption cross-section, excellent photoluminescence quantum yield, fast luminescence decay time, good processability and low toxicity. A smart choice of organic luminophores allowed us to design and synthesize a library of NOLs, absorbing from VUV to visible region and emitting at the desired wavelengths from 390 to 650 nm. They can be used as unique wavelength shifters in plastic scintillators and other applications.
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