高吸水性聚合物对高性能混凝土水化性能的影响

A. Joseph, Zainab Awadh, D. Dashti, J. Chakkamalayath
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摘要

-混凝土的理化性能和耐久性取决于养护过程的效率。水泥颗粒在固化过程中与水分子发生一系列化学反应,形成多种水泥水化产物。然而,由于混凝土中水灰比较低,如添加了胶凝材料的高性能混凝土(HPC)和超高性能混凝土(ultra-HPC),缺乏足够的水分子来完成养护过程,导致自收缩,从而产生早期微开裂。减缓收缩是可持续建设项目的强制性要求,可通过对高性能混凝土进行适当养护来实现。本文报道了高吸水性聚合物(SAP)作为内固化材料对硬化HPC在水和空气中固化28天后性能的影响,并采用N -吸附、x射线衍射(XRD)和傅里叶红外光谱(FT-IR)进行了监测。氮吸附分析表明,由于形成了更多的宏观孔隙,SAP样品的总孔隙率增加。通过x射线衍射分析,在SAP样品中检测到较高量的Ca(OH) 2,表明这些样品中形成了更多的水泥水化。
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Effect of Superabsorbent Polymer on the Hydration Properties of High-Performance Concrete
—The physico-chemical and durability properties of the concrete depend on how efficiently the curing process occurs. Cement particles undergo a series of chemical reactions with water molecules to form several cement hydration products during curing. However, the low water to cement ratio in concretes, such as high-performance concrete (HPC) and ultra-HPC with supplementary cementitious materials, lack enough water molecules for the curing process to complete, resulting in autogenous shrinkage and hence early age micro cracking. Mitigation of shrinkage is a mandatory requirement in sustainable construction projects, which can be achieved through proper curing of HPC. This paper reports the effects of superabsorbent polymer (SAP) as internal curing material on the properties of hardened HPC monitored by N 2 - adsorption, X-ray diffraction (XRD), and FT-IR spectroscopy after 28 days of curing in water and air. The N 2 adsorption analysis showed an increase in total porosity of the specimens with SAP due to the formation of more macro pores. Higher amounts of Ca(OH) 2 were detected in samples with SAP by the X-ray diffraction analysis indicating the formation of more cement hydration in those specimens.
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