限定在蛋白石基质中的二氧化钛的性质——二氧化硅纳米球的晶格填料

D. Nuzhnyy, P. Vanĕk, J. Petzelt, V. Bovtun, M. Kempa, I. Gregora, M. Savinov, R. Krupková, V. Studnička, M. Samoylovich, A. Rinkevich, A. Belyanin, S. М. Klescheva
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引用次数: 0

摘要

利用溶胶-凝胶技术,首次将BaTiO3嵌入到作为二氧化硅纳米球晶格填料的蛋白石基质中。室温红外光谱和拉曼光谱清楚地显示了铁电畸变TiO6八面体的特征振动模式,没有任何长程有序。拉曼光谱证明了蛋白石- batio3复合材料存在弥漫性铁电相变。
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Properties of BaTiO3 confined in opal matrices — lattice packings of nanospheres silica dioxide
Using the sol-gel technique, BaTiO3 was embedded in opal matrices that are the lattice packings of silica dioxide nanospheres for the first time. The room-temperature IR and Raman spectra clearly show characteristic vibrational modes of the ferroelectrically distorted TiO6 octahedra without any long-range order. Raman spectra bring evidence of a diffuse ferroelectric phase transition in the opal-BaTiO3 composite.
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