利用Ni0.1Co0.9Fe2O4纳米晶降解结晶紫

A. Ghoneim
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引用次数: 0

摘要

采用简单共沉淀法合成了Ni0.1Co0.9Fe2O4纳米晶,并用x射线衍射(XRD)、红外光谱(FT-IR)和高分辨率透射电镜(HTEM)技术对其进行了精确表征。XRD研究证实了这些纳米晶的单相立方尖晶石结构的演化。细晶尺寸R平均值为36.265 nm。FT-IR吸收光谱显示了与它们的主位和主键相关的基本吸收带。这些纳米晶体中Ni2+、Co2+和Fe3+阳离子的存在对所得参数均有影响。HTEM图像显示纳米颗粒聚集,平均粒径值为42.9 nm,略高于晶粒尺寸r。通过100瓦钨丝灯固定在~ 10 cm距离下,在可见光照射下降解水溶液中的结晶紫(CV)染料(1 × 10-5 M),获得了Ni0.1Co0.9Fe2O4纳米铁氧体的光催化活性评价。因此,这些新的超细Ni0.1Co0.9Fe2O4纳米晶体的使用为发展具有成本效益的技术提供了一条新的不可思议的途径,从而实现了相当好的废水回收模型,提高了水质,并促进了改进处理系统的卓有成效的努力。
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Utilization of the Ni0.1Co0.9Fe2O4 Nanocrystals for the Degradation of Crystal Violet
Ultrafine Ni0.1Co0.9Fe2O4 nanocrystals were synthesized by the simple co-precipitation route, and well-accurately characterized by X-ray diffraction (XRD), FT-IR spectra, and high resolution transmission electron microscopy (HTEM) technique. XRD investigation proved the evolution of the single-phase cubic spinel structure for these nanocrystals. The fine crystallite size R average value was 36.265 nm. FT-IR absorption spectra displayed the essential absorption bands that were related to their principle sites and main bonds. All the deduced parameters were affected by the presence of the Ni2+, Co2+, and Fe3+ cations in these nanocrystals. HTEM images showed accumulations for the nanoparticles, where the average particle size value was 42.9 nm and was slightly higher than the crystallite size R. Evaluation of photocatalytic activity for Ni0.1Co0.9Fe2O4 Nano-ferrites was obtained through the degradation of Crystal Violet (CV) dye (1 × 10-5 M) in aqueous solution under visible light irradiation using 100 Watt Tungsten lamp fixed at ~ 10 cm distance. As a result, usage of these new ultrafine Ni0.1Co0.9Fe2O4 nanocrystals gives a new marvellous route for the advancement of cost-effective technologies for quite good waste water recycling models, for raising water quality and for the promotion of fruitful efforts in improving treatment systems.
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