重金属在生物炭上的吸附

R. Senthilkumar, D. M. R. Prasad
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引用次数: 8

摘要

生物炭是生物材料在分解温度以上通过不同的加热方法合成的稳定的富碳产物。生物炭在各个领域的潜在用途包括改善土壤肥力、固碳、去除污染物和尽量减少废物/再利用。近年来,大量研究证实,生物炭可以成功地用于去除水溶液中的重金属离子。本章的主要目的是总结和评价生物炭对各种重金属离子的吸附能力。考虑到吸附是一种表面现象,我们将详细讨论控制生物炭形成的关键参数,包括热解温度、停留时间和原料类型。此外,还讨论了重金属离子的修复机理和影响吸附势的理化因素。在吸附研究中使用的数学模型将给予特别的重视。还将重点介绍用于增强生物炭吸附能力的改性程序。
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Sorption of Heavy Metals onto Biochar
Biochar is a stable carbon-rich product synthesized from biological materials through different heating methods above the decomposition temperature. The potential uses of biochar in various fields include soil fertility improvement, C sequestration, pollutant removal and waste minimization/reuse. In recent years, large number of research has confirmed that biochar can be used successfully for the removal of heavy metal ions from aqueous solutions. The main aim of this chapter is to summarize and assess the sorption capacity of biochar toward various heavy metal ions. Considering that sorption is a surface phenomenon, the key parameters controlling the formation of biochar including pyrolysis temperature, residence time, and feedstock type will be discussed in detail. In addition, the mechanism associated with remediation of heavy metal ions and the physicochemical factors affecting the sorption potential will be discussed. Mathematical models employed in the sorption studies will be given special importance. The modification procedures used to enhance the sorption capacity of biochar will also be highlighted.
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