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Applications of Biochar for Environmental Safety最新文献

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Enhancement of Soil Health Using Biochar 利用生物炭促进土壤健康
Pub Date : 2020-07-22 DOI: 10.5772/intechopen.92711
O. Okareh, Alaba O. Gbadebo
Over the years, the carbon-rich biochar has been used for the purpose of environmental conservation and reservation. Typically produced from varieties of materials ranging from sewage, farm produce, energy crops and agricultural waste or residues, the properties usually considered in the application of biochar include the chemical composition, porosity and stability. Contemporarily, the use of biochar has extended to its utilization in the industry, agriculture, forestry, and the natural environment. Soil fertility depends on the holistic process of managing the soil and likewise maintaining a robust biodiversity. This process involves the application of natural carbon-rich materials like biochar as soil amendments. The rapid absorption tendency of biochar, both on organic and inorganic materials has contributed immensely to the removal of excess antimicrobials from the environment. Biochar has been known to be a good enhancer of the soil due to its rich content of carbon and other nutrients good enough for the soil. Other striking effects of biochar on the soil and environment include the enhancement of the uptake of nitrogen, improvement of the soil structure, mitigation of greenhouse gases, conservation of the environment and enhancement of soil microbial community.
多年来,富碳生物炭一直被用于环境保护和保护。生物炭通常是从污水、农产品、能源作物和农业废物或残留物等各种材料中产生的,在应用生物炭时通常考虑的特性包括化学成分、孔隙度和稳定性。目前,生物炭的使用已扩展到工业、农业、林业和自然环境的利用。土壤肥力取决于管理土壤的整体过程,同样也取决于保持强健的生物多样性。这个过程包括应用天然富含碳的材料,如生物炭作为土壤改良剂。生物炭在有机和无机材料上的快速吸收趋势极大地促进了从环境中去除过量抗菌剂。众所周知,生物炭是一种很好的土壤增强剂,因为它含有丰富的碳和其他对土壤足够好的营养物质。生物炭对土壤和环境的其他显著影响包括加强对氮的吸收、改善土壤结构、减少温室气体、保护环境和增强土壤微生物群落。
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引用次数: 3
Application of Biochar for Treating the Water Contaminated with Polar Halogenated Organic Pollutants 生物炭在处理含极性卤化有机污染物水体中的应用
Pub Date : 2020-06-16 DOI: 10.5772/intechopen.92760
Barbora Kamenická, Pavel Matějíček, T. Weidlich, M. Pohořelý
Application of biochar and ionic liquid-impregnated biochar was successfully tested for removal of nonbiodegradable polar halogenated aromatic contaminants (anti-inflammatory agents diclofenac and flufenamic acid and azo dye Mordant Blue 9) from contaminated aqueous solutions. The time dependence of removal efficiencies and adsorption isotherms were evaluated, and the effect of applied ionic liquids (quaternary ammonium salts) was considered. The determined removal efficiencies of the abovementioned contaminants based on the application of biochar or biochar combined with quaternary ammonium salts were compared with the action of commercially available active carbon and/or published results obtained by the action of additional low-cost sorbents. It was demonstrated that a more laborious two-step technique, based on the initial preparation of impregnated biochar by the action of R 4 NCl with subsequent application of this modified sorbent, is much less effective than simple mixing of biochar with R 4 NCl directly in the treated wastewater solution. Experiments dealing with log P OW determination were performed using the same apparatus. An aqueous solution containing 1 mmol of studied contaminant was introduced to the round-bottomed flask (in case of studying log P OW of ion pairs, 1 mmol of R 4 NCl per mmol of -COONa or -SO 3 Na group bound in contaminant was added subsequently); the total volume of aqueous phase was adjusted to 100 mL with water saturated with octan-1-ol, and the mixture was fulfilled using 100 mL of octan-1-ol. The prepared two-phase mixture was agitated at 400 rpm overnight, and the immiscible phases were separated in a separatory funnel, and a concentration of the tested chlorinated aromatic acid sodium salt or their ion pair with R 4 N + in the aqueous phase was analyzed using VIS spectroscopy in the case of MB9 and R 4 N.MB9. In the case of NaDCF or R 4 N.DCF, the concentration in the aqueous phase was analyzed using voltammetric determination.
成功地测试了生物炭和离子液体浸渍生物炭的应用,以从污染的水溶液中去除不可生物降解的极性卤化芳香污染物(抗炎剂双氯芬酸和氟芬酸以及偶氮染料媒染剂蓝9)。考察了吸附等温线和去除效率的时间依赖性,并考虑了离子液体(季铵盐)的影响。将应用生物炭或生物炭与季铵盐结合对上述污染物的去除效率与市售活性炭的作用和/或其他低成本吸附剂的作用所获得的结果进行了比较。结果表明,通过r4ncl的作用来初始制备浸渍生物炭,然后再应用这种改性吸附剂的两步工艺比在处理后的废水中直接混合生物炭和r4ncl的效果要差得多。用相同的仪器进行了对数磷酸测定的实验。将含有1mmol所研究污染物的水溶液引入圆底烧瓶中(如果研究离子对的对数P - OW,则随后添加每mmol污染物中结合的-COONa或- so3na基团1mmol r4ncl);用辛烷-1-醇饱和水调节水相总量至100 mL,用100 mL辛烷-1-醇补齐。将制备的两相混合物在400 rpm下搅拌过夜,在分离漏斗中分离不混相,在MB9和r4n .MB9的情况下,用VIS光谱分析所测氯化芳香酸钠盐或其与r4n +离子对在水相中的浓度。在NaDCF或r4ndcf的情况下,用伏安法测定水相中的浓度。
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引用次数: 2
Biochar Effects on Amelioration of Adverse Salinity Effects in Soils 生物炭对改善土壤有害盐碱效应的影响
Pub Date : 2020-06-16 DOI: 10.5772/intechopen.92464
A. Vasconcelos
Biochar is the term given to biomass subjected to the process of change in the composition by the action of high temperatures. Advantages of biochar in soil quality have been reported, including amelioration of salinity effects. Salinity has a negative effect on soil physical properties and plant production by adversely affecting the process of plant growth, hence seed germination, nutrient uptake, and yield. Moreover, salt stress causes oxidative stress in plant and the reduction in antioxidant enzyme activities. Biochar is an amendment, which could decrease the negative effect of salt stress on crop growth and production. Application of biochar enriches mineral nutrients; improves the soil’s physical, chemical, and biological characteristics such as bulk density, hydrological properties, aggregate structure, ion exchange capacity, and microbial activity; and consequently enhances plant growth. Enhancing physical properties, biochar balances water holding capacity and air porosity in soils. Biochar promotes benefits in plant growth in saline soils through reduction in oxidation stress and in osmotic stress, lower production of phytohormones, improvement in stomatal density and conductance, improvement in seed germination, and the promotion of microbial activities. Biochar amendment can contribute to reduce salt stress in plants under saline condition due to its high salt adsorption capability.
生物炭是指在高温作用下其成分发生变化的生物质。生物炭在土壤质量方面的优势已被报道,包括改善盐度效应。盐度通过对植物生长过程产生不利影响,从而影响种子发芽、养分吸收和产量,从而对土壤物理性质和植物生产产生负面影响。此外,盐胁迫引起植物的氧化应激,使抗氧化酶活性降低。生物炭是一种可以减少盐胁迫对作物生长和生产的负面影响的改良剂。生物炭的施用丰富了矿质养分;改善土壤的物理、化学和生物特性,如容重、水文特性、团聚结构、离子交换能力和微生物活性;从而促进植物生长。生物炭增强了土壤的物理特性,平衡了土壤的持水能力和空气孔隙度。生物炭通过降低氧化胁迫和渗透胁迫,降低植物激素的产生,改善气孔密度和导度,改善种子萌发,促进微生物活动,促进盐碱地植物生长。生物炭具有较高的盐吸附能力,有助于减轻盐碱条件下植物的盐胁迫。
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引用次数: 7
Biochar Potential in Improving Agricultural Production in East Africa 生物炭在改善东非农业生产中的潜力
Pub Date : 2020-06-02 DOI: 10.5772/intechopen.92195
Godfrey Omulo
Biochar is among the environmentally friendly bio-products possible of enhancing agricultural productivity due to inherent properties. Despite the increased biochar research output, the sustainability of biochar production and its applicability in developing countries is mostly uncertain. This chapter underscores the biochar production process, its environmental usefulness, and the prediction of its potential impact on agricultural productivity in East African countries. Currently, pyrolysis technology is the most effective means of biochar production. Predominantly, biochar is useful in carbon sequestration, soil amendment, and as a solid fuel source. In-depth analysis of crop residues production in East African countries vis-à-vis the potential for biochar production and the total planted areas strongly indicate that biochar could be sustainably produced and applied in agriculture without compro-mising the forests and the environment. This knowledge is vital in guarantying the feasibility of biochar technology among policymakers as a sustainable alternative to the exorbitant mineral fertilizers.
生物炭是一种环境友好型生物产品,由于其固有的特性,可以提高农业生产力。尽管生物炭的研究产出有所增加,但生物炭生产的可持续性及其在发展中国家的适用性在很大程度上是不确定的。本章着重介绍了生物炭的生产过程、其对环境的有用性以及对东非国家农业生产力的潜在影响的预测。热解技术是目前最有效的生物炭生产手段。生物炭主要用于固碳、土壤改良和作为固体燃料来源。对东非国家作物残茬生产与-à-vis、生物炭生产潜力和总种植面积的深入分析强烈表明,生物炭可以在不损害森林和环境的情况下可持续地生产和应用于农业。这方面的知识对于确保决策者将生物炭技术作为一种可持续的替代昂贵的矿物肥料的可行性至关重要。
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引用次数: 3
Challenges of Biochar Usages in Arid Soils: A Case Study in the Kingdom of Saudi Arabia 干旱土壤中生物炭使用的挑战:沙特阿拉伯王国的案例研究
Pub Date : 2020-06-01 DOI: 10.5772/intechopen.92710
Khalid A. Alaboudi
Biochar is a carbon-rich material produced from the pyrolysis of organic biomasses in the absence of oxygen or under low-oxygen conditions. Biochar has received a great interest during the last few decades due to its beneficial roles for carbon dioxide capturing and soil fertility improvement. However, applications of biochar in arid soils are very limited, and there is a lack of knowledge on practical aspects of adding biochar to arid soils. In this chapter, we will focus on biochar applications in the Kingdom of Saudi Arabia soils as an example of arid soils. These soils are characterized by several marks, i.e., high soil pH, sand structures, high CaCO 3 contents, and low soil fertility. In addition, the unsuccessful recycling practices of agricultural and food wastes in the Kingdom of Saudi Arabia are also discussed. This chapter provides an overview of current biochar knowledge perti-nent to its application to arid soils, summarizes what is known so far about biochar and its applications in arid regions, and demonstrates the possible strategies that can be used for enhancing the practices of biochar addition to these soils.
生物炭是在无氧或低氧条件下由有机生物质热解产生的富碳物质。在过去的几十年里,生物炭因其对二氧化碳捕获和土壤肥力的有益作用而受到了极大的关注。然而,生物炭在干旱土壤中的应用非常有限,并且缺乏在干旱土壤中添加生物炭的实际方面的知识。在本章中,我们将以干旱土壤为例,重点介绍生物炭在沙特阿拉伯王国土壤中的应用。这些土壤具有土壤pH值高、砂结构、caco3含量高、土壤肥力低等特点。此外,还讨论了沙特阿拉伯王国不成功的农业和食品废物回收做法。本章概述了目前有关生物炭在干旱土壤中的应用的知识,总结了迄今为止已知的生物炭及其在干旱地区的应用,并展示了可用于加强在这些土壤中添加生物炭的实践的可能策略。
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引用次数: 1
A Mini Review of Biochar Synthesis, Characterization, and Related Standardization and Legislation 生物炭合成、表征及相关标准化与立法综述
Pub Date : 2020-05-22 DOI: 10.5772/intechopen.92621
N. Rashidi, S. Yusup
The abundance of biomass in Malaysia creates an avenue for growth of bio-economic sector through the research and development (R&D) activities on the biochar production. Biochar that is described as a carbonaceous material derived from the thermochemical process at temperature of usually lower than 700°C is promising due to its applicability in wider range of applications, such as in soil amendment (fertilizer) and as a low-cost adsorbent for the pollution remediation, apart from minimizing the solid waste disposal problems. Therefore, this chapter discusses the current trends on various production techniques of biochar from both the lignocellulosic (plantation based waste materials) and non-lignocellulosic sources, as well as the physiochemical characteristics of the resulting biochar. In addition, overview of the biochar industry in Malaysia is presented in this chapter. Lastly, recap of standardization and legislation particularly related to the biochar utilization as a soil amendment agent is included to grasp readers ’ attention prior to the large scale applications.
马来西亚丰富的生物质能通过生物炭生产的研发活动为生物经济部门的增长创造了一条途径。生物炭被描述为在温度通常低于700°C的热化学过程中产生的碳质材料,由于其适用于更广泛的应用,例如土壤改质(肥料)和作为污染修复的低成本吸附剂,除了最大限度地减少固体废物处理问题外,前景广阔。因此,本章讨论了目前从木质纤维素(基于种植园的废料)和非木质纤维素来源生产生物炭的各种技术的趋势,以及所产生的生物炭的物理化学特性。此外,本章还介绍了马来西亚生物炭行业的概况。最后,概述了生物炭作为土壤改良剂利用的标准化和立法,以便在大规模应用之前抓住读者的注意力。
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引用次数: 7
Sorption of Heavy Metals onto Biochar 重金属在生物炭上的吸附
Pub Date : 2020-05-21 DOI: 10.5772/intechopen.92346
R. Senthilkumar, D. M. R. Prasad
Biochar is a stable carbon-rich product synthesized from biological materials through different heating methods above the decomposition temperature. The potential uses of biochar in various fields include soil fertility improvement, C sequestration, pollutant removal and waste minimization/reuse. In recent years, large number of research has confirmed that biochar can be used successfully for the removal of heavy metal ions from aqueous solutions. The main aim of this chapter is to summarize and assess the sorption capacity of biochar toward various heavy metal ions. Considering that sorption is a surface phenomenon, the key parameters controlling the formation of biochar including pyrolysis temperature, residence time, and feedstock type will be discussed in detail. In addition, the mechanism associated with remediation of heavy metal ions and the physicochemical factors affecting the sorption potential will be discussed. Mathematical models employed in the sorption studies will be given special importance. The modification procedures used to enhance the sorption capacity of biochar will also be highlighted.
生物炭是生物材料在分解温度以上通过不同的加热方法合成的稳定的富碳产物。生物炭在各个领域的潜在用途包括改善土壤肥力、固碳、去除污染物和尽量减少废物/再利用。近年来,大量研究证实,生物炭可以成功地用于去除水溶液中的重金属离子。本章的主要目的是总结和评价生物炭对各种重金属离子的吸附能力。考虑到吸附是一种表面现象,我们将详细讨论控制生物炭形成的关键参数,包括热解温度、停留时间和原料类型。此外,还讨论了重金属离子的修复机理和影响吸附势的理化因素。在吸附研究中使用的数学模型将给予特别的重视。还将重点介绍用于增强生物炭吸附能力的改性程序。
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引用次数: 8
Comparative Evaluation of Hydrochars and Pyrochars for Phosphate Adsorption from Wastewater 水炭和焦炭对废水中磷酸盐吸附性能的比较评价
Pub Date : 2020-05-21 DOI: 10.5772/intechopen.92612
A. S. Sennou, S. Xiu, A. Shahbazi
Biochar represents the rich carbon residues that remains after thermally pyrolyzing or liquefying different biomass types in an oxygen-free environment. The availability of animal and agricultural wastes makes the biochar a low-cost product. It is, as a carbon-rich product, resistant to mineralization and decomposition. Biochar can be used as a multifunctional material in many applications in the environmental and agricultural sectors. Recently, a growing interest for the use of biochar in different fields is rising because of its use as a sorbent for organic and nonorganic contaminants from aqueous solutions. In this chapter, recent studies on pyrochar/hydrochar production, characterization, and phosphate adsorption are reviewed and summarized. The remediation technologies for phosphate removal from contaminated water using biochar are also discussed. The effects of reaction temperature and initial solution pH on phosphate adsorption onto biochar are compared. In addition, we highlighted the models that are used for adsorption kinetics and adsorption isotherms. ,
生物炭是指不同类型的生物质在无氧环境中热热解或液化后留下的富含碳的残留物。可利用的动物和农业废物使生物炭成为一种低成本产品。作为一种富含碳的产品,它抗矿化和分解。生物炭可以作为一种多功能材料在环境和农业领域的许多应用中使用。最近,人们对生物炭在不同领域的应用越来越感兴趣,因为它可以作为水溶液中有机和无机污染物的吸附剂。本章综述了近年来在焦炭/碳氢化合物的制备、表征和磷酸盐吸附等方面的研究进展。探讨了生物炭对污水中磷酸盐的修复技术。比较了反应温度和初始溶液pH对生物炭吸附磷酸的影响。此外,我们强调了用于吸附动力学和吸附等温线的模型。,
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引用次数: 2
The Use of Biochar as a Soil Amendment to Reduce Potentially Toxic Metals (PTMs) Phytoavailability 利用生物炭作为土壤改良剂降低潜在有毒金属(PTMs)的植物可利用性
Pub Date : 2020-05-19 DOI: 10.5772/intechopen.92611
J. Antonangelo, Hailin Zhang
The contamination of potentially toxic metals (PTMs) is widespread in the world and has negatively affected plants, humans, soil health, and environmental quality. Some metals are essential plant nutrients but they are also toxic to vegetation and aquatic live when present in high concentrations, such as Cu, Mn and Zn. Others (e.g., Pb, Cd, Cr, and As) are potential toxic metals for all organisms, and are not needed (or are toxic) for plant growth. This chapter summarizes the use of readily available biochars (BCs) to reduce PTMs phytoavailability in soils thus improving crop yields and to minimize its impact on the environment. The physicochemical and morphological properties of BCs as affected by feedstock sources and pyrolysis temperatures are discussed. The effectiveness of biochar rates on plant growth and metal fractions are also highlighted. Biochar has the potential to be used as a viable bioproduct for the remediation of contaminated soils since it reduces the phytoavailability of PTMs pollutants. Biochars produced from different feedstocks and at different pyrolysis temperatures present highly heterogeneous physicochemical and morphological properties, which can affect the effectiveness in the remediation of PTMs contaminated soils. Therefore, potential technologies need to be developed and research gaps still need to be overcome to optimize the use of BCs as a feasible alternative for remediation of metal contaminated soils.
潜在有毒金属(PTMs)污染在世界范围内广泛存在,并对植物、人类、土壤健康和环境质量产生负面影响。有些金属是植物必需的营养物质,但它们在高浓度时也对植被和水生生物有毒,例如铜、锰和锌。其他(如Pb、Cd、Cr和As)对所有生物都是潜在的有毒金属,植物生长不需要(或有毒)。本章总结了利用易得性生物炭(BCs)来降低土壤中PTMs的植物有效性,从而提高作物产量并将其对环境的影响降至最低。讨论了原料来源和热解温度对BCs的理化性质和形态性质的影响。生物炭率对植物生长和金属组分的影响也得到了强调。生物炭有潜力作为一种可行的生物产品用于污染土壤的修复,因为它降低了PTMs污染物的植物可利用性。不同原料和不同热解温度制备的生物炭具有高度不均匀的物理化学和形态特性,影响了PTMs污染土壤的修复效果。因此,需要开发潜在的技术,并克服研究空白,以优化BCs作为金属污染土壤修复的可行替代方案。
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引用次数: 7
Forest Trees for Biochar and Carbon Sequestration: Production and Benefits 用于生物炭和固碳的林木:生产和效益
Pub Date : 2020-05-11 DOI: 10.5772/INTECHOPEN.92377
D. Rockwood, Martin F. Ellis, Ru-liang Liu, Fengliang Zhao, Kyle W. Fabbro, Zhenli He, David R. Derbowka
Many tree species worldwide are suitable for making biochar (BC), with planted eucalypts in particular being very productive and extensive. Above- and below-ground carbon sequestration by Eucalyptus plantations depends on plantation management options. An intensively managed cultivar could sequester over 100 mt of C/ha at a cost of $21 – 40/mt. BC production systems ranging in size from small mobile units to large centralized facilities and many kiln technologies influence the quality and price of the BC produced as well as the ability to control emissions. While BC from wood has many applications, its use as a soil amendment in forest plantations is appealing as a long-term sequestration strategy and opportunity to grow more robust trees and increase survival rates. Research in Florida USA and elsewhere addresses responses of forest and agronomic crops to wood BC soil amendments with and without other fertilizers. In combination with the carbon sequestered through tree growth, sequestration of 2.5 mt/ha of wood BC as a soil amendment in Eucalyptus plantations has estimated costs ranging from $3.30 – 5.49/ton of C.
世界上许多树种都适合制造生物炭(BC),特别是种植的桉树产量高,分布广泛。桉树人工林的地上和地下碳固存取决于人工林管理方案。集约管理的品种每公顷可吸收100吨以上的碳,成本为21 - 40美元/吨。从小型移动装置到大型集中式设施,各种规模的碳水化合物生产系统和许多窑炉技术影响所生产碳水化合物的质量和价格以及控制排放的能力。虽然木材中的BC有许多应用,但它在森林人工林中作为土壤改良剂的用途很有吸引力,因为它是一种长期的封存策略,也是种植更健壮的树木和提高成活率的机会。美国佛罗里达州和其他地方的研究解决了森林和农用作物对木材BC土壤改良剂的反应,有和没有其他肥料。结合树木生长所吸收的碳,在桉树人工林中,作为土壤改化剂,每公顷吸收2.5公吨木材碳的成本估计在每吨碳3.30 - 5.49美元之间。
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引用次数: 4
期刊
Applications of Biochar for Environmental Safety
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