基于CVD生长MoS2薄膜的湿度传感器的制备与表征

Shiqi Guo, A. Arab, S. Krylyuk, A. Davydov, M. Zaghloul
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引用次数: 3

摘要

二维(2D)过渡金属二硫族化合物的最新进展证明了它们在化学传感器中的潜在应用。然而,化学气相沉积(CVD)生长的二硫化钼(MoS2)湿度传感器在很大程度上仍未被开发。在这项工作中,通过电子束沉积Mo层的硫化,在1cm2的蓝宝石衬底上生长了MoS2薄膜。利用原子力显微镜和拉曼光谱对二硫化钼薄膜的形貌、厚度和结晶度进行了表征。采用电子束蒸发交叉电极(ide)在二硫化钼表面上制备了双端器件。在不同湿度水平下测试了水蒸气传感,观察到由于电荷转移机制,器件对湿度的电阻响应增加。我们发现该装置具有良好的可重复性和动态迟滞性。灵敏度、快速响应和恢复证明了CVD生长MoS2薄膜可以扩大湿度和气敏应用。
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Fabrication and characterization of humidity sensors based on CVD grown MoS2 thin film
Recent advances in two-dimensional (2D) transition metal dichalcogenides have demonstrated their potential application in chemical sensors. However, the chemical vapor deposition (CVD) grown molybdenum disulfide (MoS2) humidity sensors are still largely unexplored. In this work, MoS2 thin films were grown on 1 cm2 sapphire substrates through sulfurization of e-beam deposited Mo layers. The MoS2 film morphology, thickness, and crystallinity were characterized by AFM and Raman spectroscopy. The two-terminal devices were fabricated with e-beam evaporated interdigitated electrodes (IDEs) on top of the MoS2 surface. The water vapor sensing was tested at various humidity levels with the observed increase in the device resistance response to humidity due to the charge transfer mechanism. We found the devices to be reproducible and with excellent dynamic hysteresis. The sensitivity, fast response and recovery proved that CVD growth MoS2 thin film could be scaled up for humidity and gas sensing applications.
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