磷石膏作为废物回收利用对矿物碳化法温室气体排放的影响

A. O. Gezerman
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摘要

由于人为来源和工业应用,温室气体排放到大气中,引发了全球气温的上升,称为全球变暖和相关的气候变化。磷石膏(PG)是湿法磷酸(H3PO4)生产过程的副产物,其化学成分是二水合硫酸钙(CaSO4•2H2O)和一些杂质。年PG积累量已达3亿吨,需要制定策略以确保高效、连续和批量消耗。由于PG含有大量的钙,它是一种适合用于二氧化碳捕获和储存过程的材料,以形成稳定的固体碳酸盐化合物。这一过程被称为PG的矿物碳化,通过提供利用工业副产品和实现二氧化碳捕获和储存技术的多重效益,有助于实现可持续发展目标。
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EFFECT OF PHOSPHOGYPSUM USE AS A WASTE RECYCLING ON GHG EMISSIONS BY MINERAL CARBONISATION METHOD
The release of greenhouse gas emissions into the atmosphere as a result of anthropogenic sources and industrial applications has triggered the increase in global temperatures called global warming and related climate change. Phosphogypsum (PG) is a by-product of the wet process phosphoric acid (H3PO4) production process, which chemically consists of calcium sulfate dihydrate (CaSO4•2H2O) with some impurities. Annual PG accumulation has reached 300 Mtons and a strategy is needed to ensure efficient, continuous and bulk consumption. Due to the high amount of calcium it contains, PG is a material suitable for use in CO2 capture and storage processes to form stable solid carbonate compounds. This process, called mineral carbonization of PG, contributes to sustainable development goals by providing the multiple benefits of both the utilization of an industrial by-product and the realization of CO2 capture and storage technology.
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