ZnTe:Cu薄膜和CdS/CdTe/ZnTe太阳能电池的性能

J. Tang, D. Mao, T. Ohno, V. Kaydanov, J. Trefny
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引用次数: 18

摘要

研究了Cu掺杂和沉积后退火对ZnTe薄膜和具有ZnTe:Cu/Au背接触的CdS/CdTe太阳能电池性能的影响。采用x射线衍射(XRD)、电子探针分析、原子力显微镜(AFM)、电阻率和霍尔效应测量等方法对ZnTe薄膜的结构、组成和电学性能进行了系统的研究。Cu浓度为1-6 at的ZnTe薄膜。%成功用作后接触层,填充系数超过0.70。研究了CdTe/ZnTe/Au电池在加速温度应力下的稳定性。利用I-V和C-V测量、扫描俄歇电子能谱(AES)和x射线光发射能谱(XPS)来阐明可能的降解机制。退火后,Cu和Te向Au层扩散,Au向ZnTe层扩散。
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Properties of ZnTe:Cu thin films and CdS/CdTe/ZnTe solar cells
The effects of Cu doping and post-deposition annealing on the properties of ZnTe thin films and CdS/CdTe solar cells with the ZnTe:Cu/Au back contact were investigated. The structural, compositional and electrical properties of ZnTe films were studied systematically using X-ray diffraction (XRD), electron microprobe analysis, atomic force microscopy (AFM), electrical resistivity and Hall effect measurements. ZnTe films with Cu concentrations of 1-6 at. % were used successfully as a back contact layer, providing fill factors over 0.70. The stability of CdTe/ZnTe/Au cells under accelerated temperature stress tests was investigated. I-V and C-V measurements, scanning Auger electron spectroscopy (AES) and X-ray photoemission spectroscopy (XPS) were used to clarify possible degradation mechanisms. Significant Cu and Te diffusion into Au layer and Au diffusion into ZnTe were observed after annealing.
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