无铅Sn-3.8Ag和Sn-3.8Ag-0.7 cu钎料合金在微电子封装中替代Sn-Pb钎料的蠕变

A. Torbati-Sarraf, R. Mahmudi, A. Geranmayeh, A. Baradaran-Goorani
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引用次数: 3

摘要

采用室温压痕蠕变试验研究了以Sn-37Pb为对照材料的锡基无铅Sn-3.8Ag和Sn-3.8Ag-0.7 cu合金的蠕变行为。两种方法得到的应力指数值在5.1 ~ 9.7范围内,与文献报道的同种材料室温蠕变试验结果吻合较好。从稳态蠕变速率来看,Sn-3.8Ag-0.7 cu的抗蠕变性能最高,其次是Sn-3.8Ag和Sn-Pb。在Sn-3.8Ag-0.7 cu中形成Ag3Sn和Cu6Sn5金属间化合物,在Sn-3.8Ag中形成Ag3Sn是合金抗蠕变性能优于共晶Sn-Pb合金的主要原因。
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Creep of lead-free Sn-3.8Ag and Sn-3.8Ag-0.7Cu solder alloy as replacements of Sn-Pb solder used in microelectronic packaging
Creep behavior of the tin-based lead-free Sn-3.8Ag and Sn-3.8Ag-0.7Cu alloys together with Sn-37Pb, as the material for comparison, was studied by impression and indentation creep testing at room temperature. Stress exponent values in the range 5.1 to 9.7, obtained by the two methods, were in good agreement with each other and with those determined by room-temperature creep testing of the same materials reported in the literature. Among all tested materials, as indicated by their steady-state creep rates, Sn-3.8Ag-0.7Cu showed the highest creep resistance followed by Sn-3.8Ag and Sn-Pb. The formation of Ag3Sn and Cu6Sn5 intermetallics in Sn-3.8Ag-0.7Cu, and Ag3Sn in Sn-3.8Ag are the main cause of improved creep resistance of the alloys over the eutectic Sn-Pb alloy.
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