在高于水冰升华点的压力和温度下沉积超光滑银纳米层

T. Stefaniuk, P. Wróbel, T. Szoplik
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引用次数: 1

摘要

提出并讨论了一种在高于水冰升华点的压力和温度下在电子束蒸发器中沉积超光滑银纳米层的新方法。我们平衡了物理气相沉积过程中涉及的几种现象的相互影响。在冷却的基片上沉积金属介电多层材料会产生温度变化时尺寸稳定性的问题。层间热膨胀系数不匹配会产生固有应力,导致金属膜开裂。基材过于强烈的冷却会导致基材上的水冰晶在低于升华相变的温度和压力下形成,升华相变发生在物质相图中的三相点以下。用均方根误差(RMS)描述的蓝宝石衬底上1nm Ge润湿膜上30nm厚Ag层的表面粗糙度达到0.5 nm。这项研究的动机是需要抑制由于表面粗糙度散射引起的等离子体激元损失。
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Deposition of ultrasmooth silver nanolayers at pressures and temperatures above the sublimation point of water ice
A new method of deposition of ultrasmooth silver nanolayers at pressures and temperatures above the sublimation point of water ice in electron-beam evaporator is proposed and discussed. We balance contradictory influences of several phenomena involved in physical vapour deposition process. Deposition of metal-dielectric multilayers on cooled substrates creates a problem with dimensional stability against temperature changes. Mismatch of thermal expansion coefficients of layers gives rise to intrinsic stress what results in metal film cracking. Too strong cooling of substrates leads to water ice crystals formation on substrates at temperatures smaller than sublimation phase transition that occurs at temperatures and pressures below a substance's triple point in its phase diagram. Surface roughness of 30 nm thick Ag layer deposited on 1 nm Ge wetting film on sapphire substrate described in terms of root mean square (RMS) error reaches 0.5 nm. This research is motivated by the need to suppress plasmon losses due to scattering on surface roughness.
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