聚乙烯醇聚合物基质中富勒烯醇形成的复合材料的核磁共振研究

A. E. Karpunin, V. Gerasimov, A. Mazur, I. Pleshakov, Y. Fofanov, O. Proskurina
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引用次数: 4

摘要

用核磁共振方法研究了多羟基化富勒烯(富勒烯醇)浸渍在柔性透明基质中的结构。以水溶性聚合物聚乙烯醇为主体材料。为了提供C60分子核自旋系统的强烈信号,填充化合物的浓度几乎达到最大允许值。观察到的13C核磁共振光谱显示了许多特征,这些特征可能可以用富勒烯醇团簇的存在来解释。
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NMR Investigation of Composite Material, Formed by Fullerenol in Polymer Matrix of Polyvinyl Alcohol
The structure, formed by polyhydroxylated fullerene (fullerenol), impregnated into a flexible transparent matrix, was studied by NMR method. As a host material water-soluble polymer - polyvinyl alcohol was used. The concentration of filling compound was almost at a maximum permissible value in order to provide intense signal of nuclear spin system of C60 molecules. The observed 13C NMR spectra demonstrated a number of characteristics, which presumably can be explained by the existence of fullerenol clusters.
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