动态光散射在聚集和凝胶中的应用

James E. Martin
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引用次数: 0

摘要

在过去的几年里,人们对聚集体和凝胶的结构产生了相当大的兴趣,这在很大程度上是由于对这些物体所表现出的分形几何的高度兴趣。当然,光散射通常用于确定分形维数,因此很自然地将散射场运行到自相关器中以找出动态情况。这个看似无辜的举动,是探索这些分形系统所表现出的不寻常动力学行为的漫长旅程的第一步。由于聚集体和凝胶的动力学是完全不同的,将它们依次讨论将会有所帮助。
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Application of Dynamic Light Scattering to Aggregation and Gelation
In the last several years there has been considerable interest in the structure of aggregates and gels, in large part due to the high interest in the fractal geometry these objects exhibit. Of course, light scattering is commonly used to determine fractal dimensions, so it is natural enough to run the scattered field into an autocorrelator to find out what the dynamics are up to. This seemingly innocent move is the first step in a long journey into the unusual dynamical behaviors exhibited by these fractal systems. Since the dynamics of aggregates and gels are quite different, it will be helpful to discuss them sequentially.
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