外贝加尔湖东部某矿床的矿石组成及自然金特征

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摘要

本文论述了位于东外贝加尔一个商业矿区西侧的芒金斯基矿群的矿石特征。这一有前景的矿床的矿石尚未得到充分的勘探,特别是在技术方面,这为研究其组成和确定天然金为其主要商业成分提供了基础。采用原子发射光谱定量分析、x射线荧光、电感耦合等离子体ICP-AES相原子吸收和原子发射分析等方法对矿石和蚀变岩的组成进行了研究。总碳和有机碳的质量分数在布拉戈维申斯克Pokrovsky Rudnik JSC中央火焰分析实验室测定。采用二氧化碳滴定法测定碳酸盐二氧化碳的比例。金的含量根据熔炼测定得到,银的含量根据原子吸收测定得到。岩石学和矿物学研究使用奥林巴斯BX-51光学显微镜进行。根据x射线衍射分析结果,对矿石样品的矿物组成进行了估计。在尼康Eclipse LV 100 POL显微镜上,利用透明和抛光薄片的微观研究数据,对粒径为-2 mm的原矿石粉碎后的物料进行定量矿物组成研究。样品经10%草酸溶液在水浴中处理后,由重量差测定氢氧化铁的含量。结果表明,该矿的赋存状态与距该矿最近的30 km矿床的矿石成分资料比较,既具有相似性和一致性,又存在一定的差异。它们的共同参数包括矿石硫化物含量相当高,化学矿物组成相似,以毒砂为主,铋的作用增强,以细金为主,形态特征相似。这一事实使我们可以把所调查的矿石视为最近矿床的单一矿石系统的一个组成部分。
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Ore composition and native gold characteristics of an ore occurrence in Eastern Transbaikalia
The article deals with the characteristics of the ores of an ore occurrence of the Munginsky cluster located on the western flank of one of the commercial fields of Eastern Transbaikalia. The ores of this promising ore occurrence are underexplored, especially in the technological aspect, which served the basis for studying their composition and characterizing native gold as their main commercial component. The composition of ores and altered rocks was studied by the following methods: atomic emission spectral quantitative analysis, X-ray fluorescence, as well as phase atomic absorption and atomic emission analysis with inductively coupled plasma ICP-AES. The mass fraction of total and organic carbon was determined in the Central Fire Assay Laboratory of JSC Pokrovsky Rudnik, Blagoveshchensk. The proportion of carbonate carbon dioxide was determined by the method of titrimetric determination of carbon dioxide. The content of gold was given according to the data of assay melting, the content of silver – according to the data of atomic absorption analysis. Petrographic and mineragraphic studies were carried out using an optical microscope Olympus BX-51. The mineral composition of the ore sample was also estimated based on the results of X-ray diffraction analysis. The quantitative mineral composition was studied on the crushed material of the original ore with a particle size of -2 mm using the microscopic study data of transparent and polished thin sections on a microscope Nikon Eclipse LV 100 POL. The content of iron hydroxides was determined from the weight difference after the sample was treated with a 10 % oxalic acid solution in a water bath. Comparison of the results obtained on the ore occurrence with the materials on the ore composition of the closest deposit located in 30 km demonstrates that on the one hand they are similar and uniform, and on the other hand they feature some differences. Their common parameters include a rather high degree of sulfide content of ores and similar chemical and mineral composition with the predominance of arsenopyrite, an increased role of bismuth as well as the predominance of fine gold and its similar morphological characteristics. This fact allows to consider the ore occurrence under investigation as an integral part of a single ore system of the closest deposit.
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