常压直流水等离子体分解1-萘酚

Yiman Jiang, Q. Lin, Chengzhou Liu, Longwei Chen, Y. Meng
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摘要

水热等离子体是废液中持久性有机污染物的有效分解方法之一,目前研究了直流(DC)水等离子体对高浓度1-萘酚的分解。实验结果表明:出水气体主要为H2(42.1 ~ 50.4%)、CO2(11.7 ~ 15.2%)、CO(3.9 ~ 76%)、CH4(0.01 ~ 0.15%),合成气含量均在49.6%以上。在电流为7A、初始浓度为500 mg/L的条件下,气体温度为5500 K。1-萘酚的分解效率、COD和TOC随电流(6A-SA)的增大而增大。在8 A电流下,1-萘酚的最大分解效率可达99.5%以上。初始浓度越高,1-萘酚的降解越低。本研究为水蒸气等离子体技术在高浓度有机废水处理中的应用提供了实验分析。
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Aqueous 1-naphthol Decomposition by DC Water Plasma at Atmospheric Pressure
Water thermal plasma is one of the effective methods to decompose persistent organic pollutants in waste liquid At present work, the decomposition of high concentration 1-naphthol in direct current (DC) water plasma was investigated. The experimental results showed that the major gaseous effluents were H2 (42.1—50.4%), CO2 (11.7—15.2%), CO (3.9—76%), CH4 (0.01—0.15%) and the content of the syngas was over 49.6%. The gas temperature was 5500 K under the condition of current at 7A and intial concentration at 500 mg/L. The decomposition efficiencies of 1-naphthol, COD and TOC were increased with the increase of the current (6A—SA). The maximum decomposition efficiency of 1-naphthol was over 99.5% at the current of 8 A. The higher initial concentration can lead to lower 1-naphthol degradation. This study provided an experimental analysis for the application of water vapor plasma technology in treatment of high concentration organic wastewater.
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