环氧基芳纶纤维与碳纳米管的多尺度复合材料

Numrah Sultan, M. Nazir, Urooj Zahra Khan, T. Subhani
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引用次数: 0

摘要

具有高强度重量比的混杂复合材料在结构应用中是非常重要的。人们正在进行一项广泛的研究,通过加入微纳米级增强剂来提高复合材料的机械性能。纳米增强材料提供了独特的增强机制,从而提高了复合材料的整体力学性能。为了研究纳米增强材料对纤维增强复合材料力学性能的影响,在环氧基上制备了一种新型的凯夫拉纤维与碳纳米管的多尺度复合材料。采用手工铺层和真空装袋相结合的方法制备了多尺度复合材料。通过紫外臭氧处理将纳米管功能化后,加入0.33wt%、0.66wt%和0.99wt%三种不同浓度的纳米管,以改善其与环氧基体的界面相互作用。采用光学、电子显微镜、拉伸、硬度、层间剪切等测试对复合材料进行了显微组织和力学性能表征。加入0.99wt%的纳米管,拉伸强度提高约45%,硬度提高约60%,层间剪切强度提高约13%。纳米管的均匀分散和对纳米管的粘附促进了纤维与基体之间的锚定作用,从而提高了材料的力学性能。
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Multiscale Composites of Kevlar Fibers and Carbon Nanotubes in Epoxy Matrix
: Hybrid composites with high strength to weight ratio are very important in structural applications. An extensive research is being carried out to enhance the mechanical properties of composites by incorporating micro and nanoscale reinforcements. The nanoreinforcements provide unique strengthening mechanisms that result in an overall high mechanical performance of composites. In order to investigate the effect of nanoreinforcements on the mechanical properties of fiber reinforced composites a novel multiscale composites of Kevlar fibers and carbon nanotubes in epoxy matrix were prepared in this research. A combination of hand layup and vacuum bagging technique was used to manufacture multiscale composites. Nanotubes at three different concentrations, i.e. 0.33wt%, 0.66wt% and 0.99wt% were incorporated after their functionalization through ultraviolet ozone-treatment to improve their interfacial interaction with epoxy matrix. The microstructural and mechanical property characterization of multiscale composites was performed by optical and electron microscopy, and tensile, hardness and interlaminar shear testing. An increase of ~45% in tensile strength was noted by incorporating 0.99wt% of nanotubes while the improvements of ~60% in hardness and ~13% rise in interlaminar shear strength were observed. The improved mechanical performance owes to the uniform dispersion of nanotubes along with their adherence to nanotubes promoting anchoring effect between fibers and matrix.
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