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Anti-Bacterial Activities of Green Synthesized ZnO and CuO Nanoparticles from Leaf Extracts of Warburgia ugandensis 绿色合成乌干达荆芥叶提取物氧化锌和氧化铜纳米颗粒的抗菌活性研究
Pub Date : 2023-07-31 DOI: 10.11648/j.nano.20231101.12
Lemeitaron Njenga, K. Ayabei, T. Akenga, Zipporah M. Onyambu, J. Kiptoo, M. Onani
: This work reports for the first time the green synthesis of zinc oxide nanoparticles (ZnO NPs) and copper oxide nanoparticles (CuO NPs) using leaf extracts of Warburgia ugandensis as encapsulating, stabilizing, and reducing agent. The green method of synthesis proved easy and less costly. The methanolic extracts contained various secondary metabolites as analyzed using gas chromatography-mass spectrometer (GC-MS). The nanoparticles (NPs) were further characterized for the confirmation of their synthesis using various techniques. Ultra violet-Visible spectrometer (UV-vis) confirmed the successful synthesis of ZnO NPs and CuO NPs with a maximum peak at 367 nm and 307.5 nm, respectively. The X-ray diffractometer (XRD) results confirmed the formation of hexagonal wurtzite ZnO NPs and monoclinic structures of CuO NPs with an average size of 21.2 nm and 12.86 nm, respectively. In addition, the Fourier transform infrared (FTIR) analysis showed the presence of various functional groups responsible for the formation of the nanoparticles. The antibacterial activity of the formulated nanoparticles was also investigated against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) bacterial strains with ZOI (Zones of Inhibition) measured in mm. The green synthesized ZnO nanoparticles using Warburgia ugandensis leaf extracts significantly revealed higher anti-bacterial potentials against E. coli (9.6 ± 0.9 mm) compared to both CuO NPs and ampicillin. This shows that they can be applied in the field of medicine to develop antibacterial agents to treat various ailments.
本文首次报道了以乌干达沃布尔叶提取物为包封剂、稳定剂和还原剂绿色合成氧化锌纳米粒子(ZnO NPs)和氧化铜纳米粒子(CuO NPs)。绿色的合成方法被证明简单且成本较低。采用气相色谱-质谱联用技术对甲醇提取物中多种次生代谢物进行了分析。纳米颗粒(NPs)的进一步表征,以确认其合成使用各种技术。紫外可见光谱(UV-vis)证实了ZnO和CuO纳米粒子的成功合成,最大峰分别在367nm和307.5 nm处。x射线衍射(XRD)结果证实了ZnO纳米粒子的六方纤锌矿结构和CuO纳米粒子的单斜结构,平均尺寸分别为21.2 nm和12.86 nm。此外,傅里叶变换红外(FTIR)分析表明,存在各种官能团负责纳米颗粒的形成。研究了该纳米颗粒对金黄色葡萄球菌(S. aureus)和大肠杆菌(E. coli)菌株的抑菌活性,并以mm为单位测定了ZOI(抑制区)。与CuO纳米颗粒和氨苄西林相比,用乌干达Warburgia叶子提取物合成的绿色纳米颗粒对大肠杆菌(9.6±0.9 mm)的抑菌活性显著提高。这表明它们可以应用于医学领域,开发抗菌剂来治疗各种疾病。
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引用次数: 0
Utilization of Algae for the Green Synthesis of Silver Nanoparticles and Their Applications 利用藻类绿色合成纳米银及其应用
Pub Date : 2023-03-09 DOI: 10.11648/j.nano.20231101.11
S. Singh, Preeti Maurya, Khushaboo Soni
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引用次数: 1
Synthesis of Silver Nanoparticles Using Dichloromethane-Methanol Flower Extract of Chrysanthemum cinerariaefolium and Its Antibacterial Activity 菊花二氯甲烷-甲醇提取物合成纳米银及其抑菌活性研究
Pub Date : 2021-02-23 DOI: 10.11648/J.NANO.20210901.11
C. Kosgei, F. Tolo, J. Matasyoh, M. Obonyo, P. Mwitari, L. Keter, James J. Owuor, Moses A. Ollengo, B. Irungu
Nanotechnology is an emerging field that has opened new horizons in nanomedicine. The use of silver nanoparticles is attracting much interest because of their antibacterial activity. This study involved synthesis of silver nanoparticles using Chrysanthemum cinerariaefolium flowers dichloromethane-methanol crude extract. The synthesized silver nanoparticles (Ag NPs) were characterized using UV-Vis spectroscopy, SEM, EDX, TEM and FTIR. The antibacterial potential of the nanoparticles was ascertained against methicillin-resistant Staphylococcus aureus (MRSA), Pseudomonas aeruginosa, Staphylococcus aureus and Shigella sonnei. This was followed by phytochemical analyses of the crude extracts. The Ag NPs were generally spherical as observed in the SEM and TEM micrographs with an average size of 26.98 nm. The UV- absorption spectrum revealed prominent peak at 430 nm while EDX analysis showed the percentage abundance of silver nanoparticle at (81.33%). The FTIR spectroscopy confirmed absorption bands of various functional groups on the surface of Ag NPs. The absorption bands were at 3472.88 cm-1, 3190.67 cm-1, 1646.61 cm-1, 1405.08 cm-1, 1109.32 cm-1 and 518.64 cm-1. Antibacterial potential of the synthesized Ag NPs showed that they were more active on S. aureus with an MIC of 31.25 µg/ml. The phytochemicals observed in the crude extracts that could have been responsible for reducing silver ions into silver nanoparticles were flavonoids, phenols, tannins and glycosides.
纳米技术是一个新兴的领域,为纳米医学开辟了新的视野。银纳米颗粒的使用因其抗菌活性而引起了人们的极大兴趣。本研究以菊花二氯甲烷-甲醇粗提物为原料合成纳米银。采用紫外可见光谱、扫描电子显微镜(SEM)、电子能谱(EDX)、透射电镜(TEM)和红外光谱(FTIR)对合成的银纳米粒子(Ag NPs)进行表征。确定了纳米颗粒对耐甲氧西林金黄色葡萄球菌(MRSA)、铜绿假单胞菌、金黄色葡萄球菌和索尼氏志贺氏菌的抗菌潜力。随后对粗提取物进行了植物化学分析。扫描电镜和透射电镜观察到,银纳米粒子总体呈球形,平均尺寸为26.98 nm。紫外吸收光谱在430 nm处有一个突出的峰,EDX分析显示纳米银的丰度为81.33%。红外光谱分析证实了银纳米粒子表面各种官能团的吸收谱带。吸收波段分别为3472.88 cm-1、3190.67 cm-1、1646.61 cm-1、1405.08 cm-1、1109.32和518.64 cm-1。结果表明,合成的Ag NPs对金黄色葡萄球菌具有较高的抑菌活性,MIC为31.25µg/ml。在粗提取物中观察到的可能负责将银离子还原成银纳米粒子的植物化学物质是类黄酮、酚类、单宁和苷类。
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引用次数: 0
On Guided Remagnetization in Layered Anoheterostructures 层状异质结构的引导再磁化研究
Pub Date : 2020-02-01 DOI: 10.11648/J.NANO.20190704.11
A. Korostil
Field-guided magnetic dynamics in magnetic multilayer nanostructures involves interconnection of the control field with localized spin states, which can occur directly or indirectly depending on the nature of the field and spin polarization. At the control electromagnetic field, this interconnection can be directly induced by the photon-induced spin-flip processes and indirectly by a bias field during antiferromagnetic exchange relaxation. The control impact of electric field and electric current on the magnetic states occurs indirectly via the spin polarization and spin current in combination with the exchange interaction of these polarized spins with localized magnetic states. The corresponding description of the magnetic dynamics is based on the modified Landau-Lifshitz equation and spin diffusion equations, taking into account the spin Hall and the inverse spin Hall effects for systems with normal metal sublayers. In the case of the magnetic nanostructures with the Rashba spin-orbit interaction in interfaces, the electric field-controlled magnetization is realized via the Rashba field-induced spin polarization, and its exchange interaction with localized magnetic states. Corresponding description is based on a tight-binding model of spin-orbit-coupled electrons exchange coupled to the localized magnetic states.
磁多层纳米结构中的场引导磁动力学涉及控制场与局域自旋态的相互连接,这取决于场和自旋极化的性质,可以直接或间接地发生。在控制电磁场下,这种互连可以由光子诱导的自旋翻转过程直接诱导,也可以由反铁磁交换弛豫过程中的偏置场间接诱导。电场和电流对磁态的控制作用是通过自旋极化和自旋电流结合这些极化自旋与局域磁态的交换作用间接发生的。相应的磁动力学描述基于修正的Landau-Lifshitz方程和自旋扩散方程,考虑了正常金属子层体系的自旋霍尔效应和逆自旋霍尔效应。对于界面中存在Rashba自旋-轨道相互作用的磁性纳米结构,电场控制磁化是通过Rashba场诱导的自旋极化及其与局域磁态的交换相互作用实现的。相应的描述是基于耦合到局域磁态的自旋轨道耦合电子交换的紧密结合模型。
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引用次数: 0
A Study on the Effect of Fibre Dimensions on the Thermal Conductivity of Pineapple Leaf Fibre Reinforced Polypropylene Composites 纤维尺寸对菠萝叶纤维增强聚丙烯复合材料导热性能影响的研究
Pub Date : 2019-12-09 DOI: 10.11648/J.NANO.20190703.11
Samuel Wadzani Gadzama, Olufemi Kashim Sunmonu, Umaru Semo Isiaku, A. Danladi
This research was carried out to study the thermal conductivity (TC) properties of pineapple leaf fibre (PALF) reinforced polypropylene (PP) composites. The pineapple leaf fibre dimensions were altered specifically at the macro, micro and nano dimensional states. It was considered that the thermal conductivity (TC) behavior of pineapple leaf fibre/polypropylene (PALF/PP) composites would be significantly higher when the pineapple leaf fibre which is the reinforcement agent undergoes dimensional changes. The study also considered the effect the fibre surface modification agents would have on the thermal behavior of the reinforced pineapple leaf fibre /polypropylene composites. The fibre surface modification agents used in this study are sodium hydroxide, zinc chloride, acetic anhydride and nitric acid. The guided plate steady state approach for determining thermal conductivity was used in this research. Results showed that the micro and nano fibrils of the reinforcing agent contributed to the enhanced thermal conductivity behavior of the reinforced pineapple leaf fibre/polypropylene composites. The results obtained also showed that the reinforced microfibrils pineapple leaf fibre /polypropylene composites and reinforced nanofibrils pineapple leaf fibre/polypropylene composites modified with nitric acid exhibits higher thermal conductivity than reinforced pineapple leaf fibre/polypropylene (PALF/PP) composites modified with acetic anhydride, zinc chloride, sodium hydroxide and the unmodified pineapple leaf fibre in descending order respectively.
本文研究了菠萝叶纤维(PALF)增强聚丙烯(PP)复合材料的导热性能。菠萝叶纤维在宏观、微观和纳米三个维度状态下发生了明显的变化。认为当菠萝叶纤维作为增强剂发生尺寸变化时,菠萝叶纤维/聚丙烯(PALF/PP)复合材料的导热性能会显著提高。研究了纤维表面改性剂对菠萝叶纤维/聚丙烯增强复合材料热性能的影响。本研究使用的纤维表面改性剂有氢氧化钠、氯化锌、乙酸酐和硝酸。本研究采用导板稳态法测定导热系数。结果表明,增强剂的微纳米纤维对增强菠萝叶纤维/聚丙烯复合材料的导热性能有一定的促进作用。结果还表明,用硝酸改性的增强菠萝叶微原纤维/聚丙烯复合材料和用硝酸改性的增强菠萝叶纳米原纤维/聚丙烯复合材料的导热系数依次高于用乙酸酐、氯化锌、氢氧化钠改性的增强菠萝叶纤维/聚丙烯复合材料(PALF/PP)和未改性的菠萝叶纤维。
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引用次数: 3
Fabrication of Electrospun Polycaprolactone/Gelatin Composite Nanofibrous Scaffolds with Cellular Responses 具有细胞响应的电纺聚己内酯/明胶复合纳米纤维支架的制备
Pub Date : 2019-11-08 DOI: 10.11648/J.NANO.20190702.11
Jaianand Kannaiyan, Saurabh Khare, S. Narayanan, Firdosh Mahuvawalla
Numerous wound care products have been investigated for skin tissue engineering. Factors which influence to skin substitute selection are condition of patient, wound depth, infection in wound. Other factors which also play role in deciding skin substitute are cost, its availability, ease of storage, required operative interventions. With perspective of Indian market, commercial available skin substitutes are either costly or their availability restricted to major cities only. A cost effective skin substitute is strongly needed to heal wounds with minimal scarring and maximum function. The aim of this study was to investigate the possibility of synthetic scaffold loaded with Wharton’s jelly derived Mesenchymal stem cells and to access the role of scaffolds in proliferation and differentiation of MSCs in-vitro, in order to achieve for the healing of wound graft substitutes with improved biological properties. As a result, WJ-MSCs were isolated, harvested and seeded on the surface of the fabricated PCL/GE nanofibrous scaffold. The biological properties and growth of MSCs were studied for anti-inflammation, cytotoxicity, cell proliferation, and SEM analysis indicated that the fabricated synthetic scaffold supported cells attachment, viability, and proliferation of cells. The characterization studies of nanofibers were studied for ATR-FTIR, XRD, TEM, viscosity, and degradation studies suggest that the nanofibrous scaffold loaded with stem cells could be an excellent tissue-engineered skin base for wound healing and skin regeneration.
许多伤口护理产品已被研究用于皮肤组织工程。影响皮肤替代物选择的因素有:患者情况、创面深度、创面感染等。决定皮肤替代品的其他因素还包括成本、可获得性、易于储存、所需的手术干预。从印度市场的角度来看,商业上可用的皮肤替代品要么昂贵,要么仅限于主要城市。迫切需要一种成本有效的皮肤替代品,以最小的疤痕和最大的功能愈合伤口。本研究的目的是探讨沃顿氏果冻衍生间充质干细胞的合成支架的可能性,并探讨支架在体外培养间充质干细胞增殖和分化中的作用,以实现具有更好生物学性能的伤口移植替代品的愈合。结果,WJ-MSCs被分离、收获并播种在制备的PCL/GE纳米纤维支架表面。研究了MSCs的抗炎、细胞毒性、细胞增殖的生物学特性和生长情况,SEM分析表明,制备的合成支架支持细胞附着、细胞活力和细胞增殖。对纳米纤维进行了ATR-FTIR、XRD、TEM、粘度和降解等表征研究,结果表明,载干细胞的纳米纤维支架可以作为一种良好的组织工程皮肤基础,用于伤口愈合和皮肤再生。
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引用次数: 4
Synthesis and Characterization of Titanium (iv) Oxide Loaded with Silver Nano Particles Thin Films 负载银纳米颗粒的氧化钛薄膜的合成与表征
Pub Date : 2019-04-23 DOI: 10.11648/J.NANO.20190701.11
S. Balogun, Afolabi Bola Abdulhamid, Y. K. Sanusi, A. Oluwaseun
This research investigates effect of annealing temperature on the optical properties of titanium dioxide loaded with silver nanoparticles (TiO2: AgNPs) thin films deposited on glass substrate by spin–coating technique. Silver nanoparticles was prepared using laguminosae-paplionodeae extracts as a reducing agent for silver nitrate and commercially available titanium (iv) oxide was used. Deposition of TiO2:AgNPs blend solution was done in different volume ratio. The blend solution volume ratio of (1:0.2) was deposited at 7 different thicknesses with different speed of revolution per minutes (rpm) for 30 seconds. Annealing of 16 samples deposited at 1000 rpm on the glass substrate was carried out at temperature range of 50°C to 425°C with 10°C interval in a tubular furnance. It is observed from the results that the peak absorption of photon energy occurred at 375°C in the visible range of the wavelength spectrum. Optimal thickness for peak absorbance of the TiO2:AgNPs blend layer occurred at 115 nm in the visible spectrum and at the corresponding spin speed of 1000  rpm. Optimized fabrication process with blend layer thickness of 115 nm yielded the best absorbance at annealed temperature of 375°C in the visible spectrum. The volume ratio of (1:0.2) gave the peak absorption at 0.75 a u. The band gap energy of the blend thin film is 3.58 eV at 375°C in the visible range of wavelength spectrum. It is revealed from the result that the light absorption, broadened absorption spectral range and thermal stability of titanium (iv) oxide film could be enhanced using silver nanoparticles. The results can be therefore used as a guideline for improving the design and fabrication of organic solar cells.
本研究采用自旋镀膜技术,研究了退火温度对二氧化钛载银纳米粒子(TiO2: AgNPs)薄膜光学性能的影响。以laguminose - paionodeae提取物为还原剂,用市售的氧化钛(iv)制备了纳米银。在不同的体积比下沉积TiO2:AgNPs共混溶液。混合溶液体积比为(1:0.2),以不同转速/分钟(rpm)沉积7种不同厚度,沉积时间为30秒。将16个样品以1000 rpm的速度沉积在玻璃基板上,在50°C至425°C的温度范围内(间隔10°C)在管状炉中进行退火。结果表明,在波长光谱可见范围内,光子能量的吸收峰出现在375℃。TiO2:AgNPs共混层的最佳吸光度峰厚度出现在可见光谱的115 nm处,对应的自旋速度为1000 rpm。优化后的制备工艺为共混层厚度为115 nm,在375°C的可见光谱退火温度下吸光度最佳。当体积比为(1:0.2)时,吸收峰为0.75 μ u。在375℃时,共混薄膜的带隙能为3.58 eV。结果表明,纳米银可以增强氧化钛膜的光吸收,拓宽吸收光谱范围,提高氧化钛膜的热稳定性。因此,这些结果可以作为改进有机太阳能电池设计和制造的指导方针。
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引用次数: 7
Investigation on the Electronic Structure of Nanosized Barium Monosilicide Films Produced by Low-energy Implantation of Ba+ Ions in Si 低能注入Ba+离子制备纳米单硅化钡薄膜的电子结构研究
Pub Date : 1900-01-01 DOI: 10.11648/j.nano.20210904.11
G. Imanova, I. Bekpulatov
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引用次数: 2
Multiscale Composites of Kevlar Fibers and Carbon Nanotubes in Epoxy Matrix 环氧基芳纶纤维与碳纳米管的多尺度复合材料
Pub Date : 1900-01-01 DOI: 10.11648/j.nano.20210902.11
Numrah Sultan, M. Nazir, Urooj Zahra Khan, T. Subhani
: Hybrid composites with high strength to weight ratio are very important in structural applications. An extensive research is being carried out to enhance the mechanical properties of composites by incorporating micro and nanoscale reinforcements. The nanoreinforcements provide unique strengthening mechanisms that result in an overall high mechanical performance of composites. In order to investigate the effect of nanoreinforcements on the mechanical properties of fiber reinforced composites a novel multiscale composites of Kevlar fibers and carbon nanotubes in epoxy matrix were prepared in this research. A combination of hand layup and vacuum bagging technique was used to manufacture multiscale composites. Nanotubes at three different concentrations, i.e. 0.33wt%, 0.66wt% and 0.99wt% were incorporated after their functionalization through ultraviolet ozone-treatment to improve their interfacial interaction with epoxy matrix. The microstructural and mechanical property characterization of multiscale composites was performed by optical and electron microscopy, and tensile, hardness and interlaminar shear testing. An increase of ~45% in tensile strength was noted by incorporating 0.99wt% of nanotubes while the improvements of ~60% in hardness and ~13% rise in interlaminar shear strength were observed. The improved mechanical performance owes to the uniform dispersion of nanotubes along with their adherence to nanotubes promoting anchoring effect between fibers and matrix.
具有高强度重量比的混杂复合材料在结构应用中是非常重要的。人们正在进行一项广泛的研究,通过加入微纳米级增强剂来提高复合材料的机械性能。纳米增强材料提供了独特的增强机制,从而提高了复合材料的整体力学性能。为了研究纳米增强材料对纤维增强复合材料力学性能的影响,在环氧基上制备了一种新型的凯夫拉纤维与碳纳米管的多尺度复合材料。采用手工铺层和真空装袋相结合的方法制备了多尺度复合材料。通过紫外臭氧处理将纳米管功能化后,加入0.33wt%、0.66wt%和0.99wt%三种不同浓度的纳米管,以改善其与环氧基体的界面相互作用。采用光学、电子显微镜、拉伸、硬度、层间剪切等测试对复合材料进行了显微组织和力学性能表征。加入0.99wt%的纳米管,拉伸强度提高约45%,硬度提高约60%,层间剪切强度提高约13%。纳米管的均匀分散和对纳米管的粘附促进了纤维与基体之间的锚定作用,从而提高了材料的力学性能。
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引用次数: 0
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American Journal of Nano Research and Applications
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