臭氧降解地表水中微囊藻的研究

Jesús J. Beltrán de Heredia Alonso, José Martín Gallardo, María del Mar Barrado Moreno
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摘要

由于一般而言,大陆地表水水库中藻类的浓度逐渐增加,因此有必要在饮用水处理厂采用先进技术,以减少/消除存在的藻类。藻群的这种降解还会导致毒素的破坏,这些毒素在气化过程中可能被释放到水介质中。本文研究了微囊藻在4 mol/L环境下的降解。可以观察到,该变量对藻类的降解有很强的正向影响。因此,当臭氧浓度为5.4 × 10−4 mol/L时,4种基质降解时间为30 min,降解完全,而当臭氧浓度为4.5 × 10−5 mol/L时,降解率在80% ~ 90%之间。在两种类型的臭氧化制度下进行了动力学研究。在均相状态下,该模型既包括臭氧在水中的自分解,也包括臭氧与藻类的直接反应;在非均相状态下,该模型还包括臭氧从气相到液相的传质。利用MATLAB软件对模型进行解析,得到了该藻类的动力学降解常数在9 × 10−4 (Villar del Rey水库)和1.4 × 10−3(蒸馏水)L/(µg叶绿素min)之间。
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Degradation of Microcystis sp. in Surface Water by Ozone
: Due to the gradual increase in the concentration of algae, in general, in continental surface water reservoirs, it is necessary to incorporate advanced technologies in drinking water treatment plants with a view to reduce/eliminate the algae present. This degradation of the algal mass will additionally lead to the destruction of the toxins that could be released into the aqueous medium during the course of potabilisation. In this work, degradation assays of Microcystis sp. in surface 4 mol/L. It is observed that this variable has a strong positive influence on the degradation of the algae. Thus, for a time of 30 minutes, the degradation is total with the four matrices for the ozone concentration of 5.4 × 10 − 4 mol/L, while for the concentration of 4.5 × 10 − 5 mol/L the degradation is between 80 and 90%. A kinetic study has been carried out in both types of ozonation regime. In the case of the homogeneous regime, the model includes both the self-decomposition of ozone in water and the direct reaction of ozone with the algae, and in the case of the heterogeneous regime, the mass transfer of ozone from the gas to the liquid phase is also incorporated. The resolution of the model with the MATLAB software leads to a value of the kinetic degradation constant of the alga between 9 × 10 − 4 (Villar del Rey reservoir) and 1.4 × 10 − 3 (distilled water) L/( µ g chlorophyll min).
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