研究了芦荟提取物与氧化铁锈纳米颗粒混合对亚甲基蓝染料的降解和光催化活性

D. A. Kadhim, M. Abid, W. Salih
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摘要

氧化铁纳米颗粒(IONPs)因其成本低、安全有效而在环境领域得到了广泛的应用。本研究通过铁锈和芦荟凝胶植物提取物在100℃的高压灭菌槽中水热反应18小时,成功地制备了IONPs。离子载体的产生是为了防止亚甲基蓝染料(MB)降解对人体健康的有害影响。采用XRD、FE-SEM和FT-IR光谱对离子ps进行了表征。XRD分析了600℃(Fe3O4) NPs的小晶粒尺寸(19 nm)和(反立方)结构(磁铁矿),而300℃(Fe902O) NPs的小晶粒尺寸为28 nm。FESEM结果表明,芦荟提取物在600℃下制备的(Fe3O4)纳米粒子的粒径为(26.80 ~ 37.96)nm,而在300℃下制备的Fe902O(浮氏体)纳米粒子的粒径为(31.63 ~ 130.3)nm。FT-IR光谱解释了Fe3O4 NPs(磁铁矿)在600°C时与芦荟的强吸收带。在(650)cm-1处有较高的吸收峰,对应于300℃下Fe902O NPs的Fe-O系列。当光谱出现吸收峰时,表明吸收峰较强。氧化铁NPs在环境处理中用于去除MB染料的时间较短。40分钟的IONPs (Fe3O4)对MB染料的降解效率(95%)为300℃,而75分钟的IONPs (Fe902O)与芦荟在600℃下对MB染料的降解效率(91%)。
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Study the degradation and photocatalytic activity of the methylene blue dye by mixing the Aloe vera extract with rust iron oxide nanoparticle
Iron oxide nanoparticles (IONPs) have been widely used in environmental applications due to their low cost, safety, and effectiveness. This research successfully produced IONPs by hydrothermally reacting iron rust and Aloe vera gel plant extract at 100 oC for 18 hours in an autoclave cell. IONPs were produced to prevent detrimental effects on human health by degrading methylene blue dye (MB). IONPs were characterized by XRD, FE-SEM, and FT-IR spectroscopy. The small crystalline size (19 nm), and (inverse cubic) structure (magnetite) of (Fe3O4 NPs) 600 oC were explained by measurements of XRD, whereas small crystalline (Fe902O) NPs of 300 oC were of 28 nm. FESEM revealed that the particle size of (Fe3O4) NPs at 600 oC using an aloe vera extract was (26.80 to 37.96) nm, whereas Fe902O (wustite) at 300 oC was tiny and crystalline at (31.63 to 130.3) nm. The strong absorption band for Fe3O4 NPs (magnetites) at 600 °C with aloe vera is explained by the FT-IR spectra. The absorption peak was high at (650) cm-1 and corresponded to the Fe-O series of Fe902O NPs at 300 oC. When the spectra showed the absorption peak, it was strong. Iron oxide NPs have been used for a short time in environmental treatment to remove MB dye. For 40 minutes of IONPs (Fe3O4), the results of degradation effectiveness (95%) were 300 oC for MB dye, but degradation efficiency (91%) was 75 minutes of IONPs (Fe902O) with aloe vera at 600 oC for MB dye.
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