一种具有环境应用价值的Analcima天然沸石的微观结构和形态性质

C. Hernández, J. Olmos, F. Vergara, Astrid Loré, L. Arza, Cenobio Cárdenas, Ildemán Abrego, Miguel Angel Hernández Espinosa
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引用次数: 0

摘要

本文介绍了一种来自巴拿马奇里基省的天然沸石的微观结构和形态表征结果。通过x射线衍射和Rietveld精化,确定了沸石天然Analcima的存在,但与其他相关矿物,从其地质构造的角度来看,主要有:钠长石、透辉石和Sanidine。利用傅里叶变换红外光谱(FTIR)技术证实了Analcima的存在。结合沸石的热处理,研究其FTIR光谱的变化,可以推断,Analcima(及其其他成分)在600℃以下是稳定的,因为它的吸收光谱没有明显的变化,而在更高的温度下,与结晶水键相关的吸收带逐渐减少,直到1000℃,它们消失。扫描电镜分析显示了混合形态,包括柱状、片状和多边形颗粒的结构,以及直径约5微米的空腔。一个特别的细节是,当沸石热处理到1000℃时,形貌没有明显变化,这表明沸石的微观结构是稳定的。
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Microstructural and Morphological Properties of an Analcima Natural Zeolite of Interest for Environmental Applications
It presents the results of the microstructural and morphological characterization of a natural Zeolite from the province of Chiriqui, Panama. By X-ray diffraction and Rietveld refinement, the presence of Zeolite Natural Analcima is determined, but with other related minerals, from the point of view of their geological formation, such as: Albite, Diopside and Sanidine mainly. The use of the Fourier Transform Infrared Spectroscopy (FTIR) technique confirms the presence of the Analcima. Combining thermal treatments to the Zeolite and studying the variation of its FTIR spectra, it is inferred that Analcima (and its other constituents) is stable up to 600 °C, since its absorption spectrum does not change significantly, while at higher temperatures absorption bands related crystalline water bonds, progressively decrease up to 1000 °C, where they disappear. The evaluation of the Scanning Electron Microscopy Analcime reveals a mixed morphology, consisting of structures in the form of columns, sheets and polygonal particles, as well as cavities of approximately 5 micrometers in diameter. A particular detail is that with the heat treatment of the Zeolite up to 1000 ° C, the morphology does not change significantly, which suggests the microstructural stability of the Zeolite.
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