木质素的抗静电作用;作为一种高性价比的添加剂

Fatma Demir, Mertcan Özel, Bilge Baytekin
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摘要

木质素是一种复杂的三维有机聚合物,由羟基、甲氧基、羰基和羧基取代而没有确切的化学结构。木质素存在于高等植物中,主要存在于硬木和软木植物的木质组织中,是世界上含量第二丰富的聚合物,它为植物提供了独特的强度和弹性特性。木质素主要是作为造纸工业制浆过程中的副产品获得的,每年有数百万吨的木质素主要是为了获取能源而燃烧。这种丰富的聚合物还具有一些非常有用的特性,例如具有抗氧化性能、无定形和像热塑性塑料一样的性能。因此,它可以方便地用作低分子量化学品、分散剂、乳化剂和聚合物材料添加剂的来源。由于聚合物、电子、航天、医药等许多行业都在处理静电沉积带来的困扰;本研究的目的是利用木质素作为弹性体的抗静电剂,提供一种廉价和环保的方法来避免静电电荷的形成。用不同的技术对天然木质素掺杂弹性体进行了表征,然后对木质素掺杂样品进行了表面电荷密度测量(净电荷和放电时间测量),以评估其抗静电性能的程度,并将结果与未掺杂样品进行了比较。致谢:我们感谢土耳其科学技术研究理事会(TÜBİTAK)(项目编号:116Z523)的资助和财政支持。
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ANTISTATIC EFFECT OF LIGNIN;AS A COST-EFFECTIVE ADDITIVE
Lignin is a complex 3D organic polymer, consist of hydroxyl, methoxyl, carbonyl and carboxyl substitutions without an exactly known chemical structure. Occurring in higher plants, mainly in woody tissues of hardwood and softwood plants, lignin is the world’s second most abundant polymer which provides unique strength and elastic properties of the plants. Predominantly, lignin is obtained as a byproduct during the pulp production of the paper industry and millions of tons of lignin per year are mostly burned simply for energy. Such an abundant polymer also has some very useful features such as having antioxidant properties, being amorphous and behaving like thermoplastics. Thus, it is convenient to be used as a source of low molecular weight chemicals, dispersants, emulsifiers, and additives for polymeric materials. Since many industries such as polymer, electronics, space, medicine and etc. are dealing with troubles caused by static electric deposition; it is aimed, in this study, to provide a cheap and environment friendly method for avoiding electrostatic charge formation using lignin as an antistatic agent for elastomers. Elastomers doped with isolated natural lignin are characterized by various techniques and then, lignin doped samples are analyzed for surface charge density measurements (net charge and discharge time measurements) to assess the extent of antistatic behavior and the results are compared with the undoped samples. Acknowledgments: We acknowledge The Scientific and Technological Research Council of Turkey (TÜBİTAK) (Project No: 116Z523) for the grant and the financial support.
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