Rare earth elements in Fe-Mn nodules from southern Baltic Sea – a preliminary study

Between 1976–1990, the Polish Geological Institute performed geological works in the Polish Maritime Areas. During these works, 260 occurrences of concretions were recorded from 7,500 sampled sites. In 1980, the threshold that separates the Bornholm Basin from the Słupsk Furrow was mapped. Numerous Fe-Mn nodules on the seabed were found in that area. The results of detailed analyses of nodule samples collected from four sites are presented in this paper. Analyzed nodules represent discoidal D, irregular I, and transitional D-I types. The nodules are characterized by varied chemical composition of main oxides (Fe, Mn). The maximum Fe2O3 content is 26.63% and MnO 23.18%. Total average amount of REE + Y in the samples is approximately 165.11 ppm, ΣLREE 145.72 ppm and ΣHREE 19.39 ppm. The LREE content is enriched in comparison to HREE. The majority of nodules consist of Fe-Mn oxy-hydroxide minerals with very low crystallinity (practically amorphous phases). The main confirmed Mn-phases are birnessite and todorokite. Other main components of the nodules are: detrital quartz, albite, microcline, glauconite and muscovite, clinochlore, and clay minerals: illite and chlorite. The rate of growth of Fe-Mn nodules has been estimated using a cobalt chronometer. The nodule growth rate ranges from 0.006 to 0.134 mm/yr –1. Based on the Fe, Mn and (Cu + Co + Ni) contents, the origin of studied nodules is determined as hydrogenetic, while using REE (Cesn/Cesn · vs. Nd) – as diagenetic.