杂化生物聚合物的激光发射-光致变色聚合物结构

L. Sznitko, J. Myśliwiec, A. Sobolewska, S. Bartkiewicz, A. Miniewicz
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摘要

本文研究了基于光致变色聚合物和生物聚合物体系的两层结构的放大自发发射和激光现象。顶层由脱氧核糖核酸与十六烷基三甲基氯化铵阳离子表面活性剂分子(DNA-CTMA)掺杂罗丹明6G (Rh6G)激光染料制成,作为激光发射的“活性”层。对于底层,我们选择了L-21+TDI光致变色聚合物,其中表面浮雕光栅(SRG)采用全息方法刻刻,以实现有效的“有源”层的折射率调制。采用倍频纳秒脉冲Nd∶YAG激光(λ = 532 nm)激发样品。激光发射的阈值能量密度ρ = 1.8 mJ/cm2, ASE的阈值能量密度ρ = 3.5 mJ/cm2。
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Laser emission in a hybrid biopolymer — Photochromic polymer structure
We present studies on amplified spontaneous emission (ASE) and lasing phenomena obtained in two layers structure based on photochromic polymer and biopolymer system. A top layer was made of the deoxyribonucleic-acid with cetyltrimethyl-ammonium chloride cationic surfactant molecules (DNA-CTMA) doped with the Rhodamine 6G (Rh6G) laser dye and served as an “active” layer for laser emission. For a bottom layer we have chosen the L-21+TDI potochromic polymer in which the surface relief grating (SRG) was inscribed using holographic method to achieve effective refractive index modulation of the “active” layer. For the sample excitation doubled in frequency nanosecond pulse Nd∶YAG laser light (λ = 532 nm) was used. The threshold energy density of laser emission was ρ = 1.8 mJ/cm2 and for ASE ρ = 3.5 mJ/cm2.
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