喷墨印刷叠层MIM薄膜固态柔性超级电容器的特性研究

B. Morshed, Moriom R. Momota, Tomoko Fujiwara
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电能存储需求已经发展到轻型便携式设备,如电动汽车、无人机、机器人、可穿戴设备等。目前的锂离子电池或锂聚电池等技术已不能满足未来的需求。我们一直在开发一种新型超级电容器来克服这一技术障碍。我们的超级电容器采用喷墨打印(IJP)技术制造,该技术使用非常精确的基于MEMS的墨盒在平面基板上打印薄膜。我们之前已经演示了金属-绝缘体-金属(MIM)电容器的制造和模拟,以及堆叠MIM超级电容器的制造。本文给出了IJP堆叠型MIM超级电容器的电学表征(如充放电周期)和扫描电镜图像。电学特性验证了超级电容器的电荷存储能力。我们对样品进行了高达20v充电电压的测试。相应的存储电荷可高达40nc,电荷密度为17.4 $\mathbf{C}/\mathbf{m}^{3}$。这些固态IJP堆叠MIM超级电容器具有高能量密度和长时间使用的灵活性,可适用于电动汽车,可穿戴设备,植入式,无人机和其他储能应用。
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Characterization of Inkjet-Printed Stacked MIM Thin-film Solid-State Flexible Super-Capacitor
Electrical energy storage need has evolved to lightweight and portable devices such as electric vehicle, drones, robotics, wearables, etc. Current technology of batteries such as Li-Ion or Li-Poly are not able to meet the requirement for future. We have been developing a new type of supercapacitor for this technological barrier. Our supercapacitors are fabricated with inkjet-printing (IJP) technique that uses very precise MEMS based cartridge to print thin-films on planar substrates. We have previously demonstrated metal-insulator-metal (MIM) capacitor fabrication and simulation, as well as stacked MIM supercapacitor fabrication. In this paper, we present electrical characterization (such as charging-discharging cycles) and scanning electron microscopy image for IJP stacked MIM supercapacitor. The electrical characterization validates the charge storage capability of the supercapacitor. We have tested the samples for up to 20 V charging voltage. The corresponding stored charge can be as high as 40 nC, and the charge density is 17.4 $\mathbf{C}/\mathbf{m}^{3}$. These solid-state IJP stacked MIM supercapacitors are flexible with high energy-density and safe for prolonged use which can be applicable in electric vehicles, wearables, implantable, drones, and other energy storage applications.
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