对称应变Si/Ge超晶格的温度相关热导率

T. Borca-Tasciuc, Jianlin Liu, T. Zeng, Weili Liu, D. Song, C. Moore, Gang Chen, Kang L. Wang, M. Goorsky, T. Radetić, R. Gronsky
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摘要

近年来,有实验证据表明,GaAs/AlAs、Si/Ge和Bi2Te3/Sb2Te3超晶格的热导率显著降低。先前报道的Si/Ge超晶格的实验研究是基于金属氧化物化学气相沉积(MOCVD)在GaAs衬底上与Ge缓冲液生长的样品。在这项工作中,我们给出了由分子束外延(MBE)生长的对称应变Si/Ge超晶格的热导率随温度变化的实验结果,作为超晶格周期和生长温度的函数。导热系数测量采用差分3ω方法进行。在这种技术中,通过实验确定了超晶格薄膜上的温降,并用于估计薄膜的导热性。利用透射电子显微镜(TEM)研究了超晶格的质量以及生长温度对超晶格结构的影响。在所研究的所有超晶格中,测得的导热系数值均低于Si0.5Ge0.5合金。此外,测量的高位错密度40Å周期Si/Ge超晶格的导热系数与计算的组成块体材料的最小导热系数相当。
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Temperature Dependent Thermal Conductivity of Symmetrically Strained Si/Ge Superlattices
Experimental evidence for a significant thermal conductivity reduction has been reported in recent years for GaAs/AlAs, Si/Ge, and Bi2Te3/Sb2Te3 superlattices. Previously reported experimental studies on Si/Ge superlattices are based on samples grown by metal oxide chemical vapor deposition (MOCVD) on GaAs substrates with Ge buffers. In this work, we present experimental results on the temperature dependent thermal conductivity of symmetrically strained Si/Ge superlattices grown by molecular beam epitaxy (MBE) as a function of the superlattice period and the growth temperature. Thermal conductivity measurements are performed using a differential 3ω method. In this technique, the temperature drop across the superlattice film is experimentally determined and used to estimate the thermal conductivity of the film. Transmission electron microscopy (TEM) is employed to study the quality of the superlattice and the influence of the growth temperature on the superlattice structure. For all the superlattices studied, the measured thermal conductivity values are lower than that of the Si0.5Ge0.5 alloy. Furthermore, the measured thermal conductivity of a 40Å period Si/Ge superlattice with high dislocation density is comparable to the calculated minimum thermal conductivity of the constituent bulk materials.
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