Tao Zou, Dongqiao Zhang, Kuangyu Shen, Zhenduo Huang, Tao Xu, Xiaohong Peng, He Zhang, Yanliang Du, Luyi Sun
{"title":"基于对甲苯磺酸掺杂聚吡咯热电效应的阻燃防火棉复合织物","authors":"Tao Zou, Dongqiao Zhang, Kuangyu Shen, Zhenduo Huang, Tao Xu, Xiaohong Peng, He Zhang, Yanliang Du, Luyi Sun","doi":"10.1007/s42114-023-00781-7","DOIUrl":null,"url":null,"abstract":"<div><p>Recently, many efforts have been devoted to studying early-stage fire-warning materials (EFWMs). Among those, thermoelectric effect-based EFWM (TE-EFWMs) are particularly attractive because they are self-powered and intrinsically sensitive to temperature. However, none of the reported fire-warning response times of TE-EFWMs can reach 1.0 s. Herein, flame-retardant composite cotton fabrics with speedy and repeatable fire warning function (denoted as CF-TE-FR) were constructed by in-situ polymerized polypyrrole (PPy) doped with P-toluenesulfonic acid (PTSA) and a flame retardant composite layer composed of sodium montmorillonite (MMT) and ammonium polyphosphate (APP). The fire warning performance of CF-TE-FR was effectively enhanced through PTSA doping, and the fire warning response time was shortened with an increasing concentration of PTSA. The fire warning indicator could be triggered as fast as 0.8 s when the molar ratio of PTSA to pyrrole monomer reached 1:3. Meanwhile, all the CF-TE-FR samples could release the fire-warning signals repeatedly. This work proposes a facile approach to the fabrication and application of organic thermoelectric polymer-based materials with ultrafast fire-warning response, repeatable fire-warning capability, and excellent flame retardancy.</p><h3>Graphical abstract</h3><p>Flame-retardant cotton fabrics based on the thermoelectric effect of polypyrrole demonstrate speedy and repeatable fire warning function.</p>\n <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\n </div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 6","pages":""},"PeriodicalIF":23.2000,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Flame-retardant and fire-warning cotton composite fabrics based on the thermoelectric effect of polypyyrole doped with P-toluenesulfonic acid\",\"authors\":\"Tao Zou, Dongqiao Zhang, Kuangyu Shen, Zhenduo Huang, Tao Xu, Xiaohong Peng, He Zhang, Yanliang Du, Luyi Sun\",\"doi\":\"10.1007/s42114-023-00781-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Recently, many efforts have been devoted to studying early-stage fire-warning materials (EFWMs). Among those, thermoelectric effect-based EFWM (TE-EFWMs) are particularly attractive because they are self-powered and intrinsically sensitive to temperature. However, none of the reported fire-warning response times of TE-EFWMs can reach 1.0 s. Herein, flame-retardant composite cotton fabrics with speedy and repeatable fire warning function (denoted as CF-TE-FR) were constructed by in-situ polymerized polypyrrole (PPy) doped with P-toluenesulfonic acid (PTSA) and a flame retardant composite layer composed of sodium montmorillonite (MMT) and ammonium polyphosphate (APP). The fire warning performance of CF-TE-FR was effectively enhanced through PTSA doping, and the fire warning response time was shortened with an increasing concentration of PTSA. The fire warning indicator could be triggered as fast as 0.8 s when the molar ratio of PTSA to pyrrole monomer reached 1:3. Meanwhile, all the CF-TE-FR samples could release the fire-warning signals repeatedly. This work proposes a facile approach to the fabrication and application of organic thermoelectric polymer-based materials with ultrafast fire-warning response, repeatable fire-warning capability, and excellent flame retardancy.</p><h3>Graphical abstract</h3><p>Flame-retardant cotton fabrics based on the thermoelectric effect of polypyrrole demonstrate speedy and repeatable fire warning function.</p>\\n <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\\n </div>\",\"PeriodicalId\":7220,\"journal\":{\"name\":\"Advanced Composites and Hybrid Materials\",\"volume\":\"6 6\",\"pages\":\"\"},\"PeriodicalIF\":23.2000,\"publicationDate\":\"2023-10-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Composites and Hybrid Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s42114-023-00781-7\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Composites and Hybrid Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s42114-023-00781-7","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Flame-retardant and fire-warning cotton composite fabrics based on the thermoelectric effect of polypyyrole doped with P-toluenesulfonic acid
Recently, many efforts have been devoted to studying early-stage fire-warning materials (EFWMs). Among those, thermoelectric effect-based EFWM (TE-EFWMs) are particularly attractive because they are self-powered and intrinsically sensitive to temperature. However, none of the reported fire-warning response times of TE-EFWMs can reach 1.0 s. Herein, flame-retardant composite cotton fabrics with speedy and repeatable fire warning function (denoted as CF-TE-FR) were constructed by in-situ polymerized polypyrrole (PPy) doped with P-toluenesulfonic acid (PTSA) and a flame retardant composite layer composed of sodium montmorillonite (MMT) and ammonium polyphosphate (APP). The fire warning performance of CF-TE-FR was effectively enhanced through PTSA doping, and the fire warning response time was shortened with an increasing concentration of PTSA. The fire warning indicator could be triggered as fast as 0.8 s when the molar ratio of PTSA to pyrrole monomer reached 1:3. Meanwhile, all the CF-TE-FR samples could release the fire-warning signals repeatedly. This work proposes a facile approach to the fabrication and application of organic thermoelectric polymer-based materials with ultrafast fire-warning response, repeatable fire-warning capability, and excellent flame retardancy.
Graphical abstract
Flame-retardant cotton fabrics based on the thermoelectric effect of polypyrrole demonstrate speedy and repeatable fire warning function.
期刊介绍：
Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field.
The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest.
Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials.
Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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