可3D打印柔性丙烯酸酯基树脂的制备与表征

Melinda Szalóki, Aaisha Akhtar Kabli, Csaba Hegedűs
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摘要

本研究的目的是制备一种丙烯酸酯基3D可打印树脂,该树脂在光聚合后显示出柔性性能,并表征聚合物体的机械物理化学性质。实验树脂中丙烯酸丁酯(BA)和聚氨酯二甲基丙烯酸酯(UDMA)的质量比为7:3,苯二(2,4,6-三甲基苯甲酰)氧化膦(BAPO)的质量比为0.2% w/w,4 -(二甲氨基)苯甲酸乙酯的质量比为0.4% w/w。拉伸强度测量采用内含子5544进行。固化时间分别为1、2和5 min。利用FT-IR光谱对试样的上下表面进行了转换度(DC)测量。树脂的抗拉强度随聚合时间的延长而增加。这背后是更高的聚合度,这也得到了转化数据的支持。实验树脂的试验打印表明,该基质可以应用于SLA 3D打印机。
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Preparation and characterization of 3D printable flexible acrylate-based resin
The aim of this study was to prepare an acrylate-based 3D printable resin that showed flexible properties after photopolymerizationand to characterize mechanical-physicochemical properties of polymerized objects. The experimental resincontained butyl acrylate (BA) and urethane dimethacrylate (UDMA) in 7:3 weight ratio, phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO) in 0.2 %w/w and ethyl 4-(dimethylamino) benzoate in 0.4 %w/w. Tensile strength measurementswere performed by Intron 5544. The curing times were 1, 2 and 5 min. FT-IR spectroscopy was used for the degreeof conversion (DC) measurements on the top and bottom surfaces of specimens. The tensile strength data of resinincreased with polymerization time. Behind this is a higher degree of polymerization, which is also supported by the conversiondata. A trial printing of experimental resin revealed that this matrix can be applied in an SLA 3D printer.
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