化石燃料加工产物含氧官能团树脂的研究进展

Yuriy Prysiazhnyi, Oleg Grynyshyn, Serhiy Pyshyev, Bohdan Korchak, Michael Bratychak
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引用次数: 0

摘要

以煤焦化液产品(CCLP)中的烃类热解馏分、重质汽油馏分和轻质煤焦油馏分为原料合成含氧官能团树脂。利用上述有机原料加工的非靶产物和/或副产物可制得各种类型的引发剂和工业单体:通过引发低聚法(从C9馏分)-含官能团的石油聚合物树脂;通过自由基冷却聚合(由CCLP)(与RPKV) -具有官能团的香豆素独立树脂。研究了控制含官能团树脂合成过程的主要因素,包括工艺温度、反应时间和反应混合物组成对树脂定量和定性特性的影响。红外光谱分析了合成树脂的结构,确定了环氧、羧基、羟基和甲基丙烯酸酯等官能团的存在。
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Resins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements
To synthesize resins with oxygen-containing functional groups the C9 fractions of hydrocarbon pyrolysis, heavy gasoline, and light coal tar fraction obtained from coal coking liquid products (CCLP) were used. Various types of initiators and industrial monomers were obtained using the above-mentioned non-target and/or by-products of organic raw materials processing: by the initiated oligomerization method (from C9 fractions) – petroleum polymer resins with functional groups; by radical cooligomerization (from CCLP) (with RPKV) – coumarone-indene resins with functional groups. The influence of the main factors controlling the synthesis process of resins with functional groups on their quantitative and qualitative characteristics was studied, including the process temperature, duration, and the reaction mixture composition. The structure of the synthesized resins was analyzed by IR spectroscopy, and the presence of epoxy, carboxyl, hydroxyl, and methacrylate functional groups was confirmed.
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