姜黄提取物复合染料制备染料敏化太阳能电池(DSSC)根茎和红枣(<i>Anredera cordifolia</i>)叶片浸提液的pH值

IF 1 Q4 CHEMISTRY, MULTIDISCIPLINARY Indonesian Journal of Chemistry Pub Date : 2023-08-15 DOI:10.22146/ijc.77860
Pirim Setiarso, Rifanda Viantiano Harsono, Nita Kusumawati
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引用次数: 1

摘要

研究了从黄姜黄和堇青花中提取染料的组合制备染料敏化太阳能电池(DSSC)。每种染料在pH为1 ~ 13的条件下提取,然后用紫外可见光谱对其进行表征。用循环伏安法测定了带隙能。黄腐根提取物的紫外可见光谱显示了姜黄素成分的存在。紫外可见光谱分析表明,堇青花中含有叶绿素和少量花青素。酸相(pH 1, 0.66 eV)和碱相(pH 13, 0.43 eV)带隙能最小。在pH为7的酸相和pH为12的碱相中,栀子提取物的能带能最小值分别为0.96 eV和0.65 eV。当堇青花和黄芍提取物混合时,最佳的组成比为pH 7:pH 1(3:2≈pH 1.7)和pH 12:pH 13(1:4≈pH 12.6)。将该混合物应用于DSSC,效率分别为0.096和0.147%。
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Fabrication of Dye Sensitized Solar Cell (DSSC) Using Combination of Dyes Extracted from Curcuma (<i>Curcuma xanthorrhiza</i>) Rhizome and Binahong (<i>Anredera cordifolia</i>) Leaf with Treatment in pH of the Extraction
Research on Dye Sensitized Solar Cell (DSSC) fabrication has been carried out using a combination of dyes extracted from Curcuma xanthorrhiza and Anredera cordifolia. Each dye was extracted by treating pH 1 to 13 and then characterized using UV-Vis spectroscopy. The band gap energy was determined by using the cyclic voltammetric method. The UV-Vis spectrum of C. xanthorrhiza extract reveals the presence of curcumin components. The UV-Vis spectrum of A. cordifolia indicates the presence of chlorophyll and a trace of anthocyanin. C. xanthorrhiza extract had the least band gap energy in the acid phase, pH 1, at 0.66 eV, and the alkaline phase, pH 13, at 0.43 eV. The minimum band gap energy of A. cordifolia extract was determined to be 0.96 eV in the acid phase, pH 7, and 0.65 eV in the alkaline phase, pH 12. When A. cordifolia and C. xanthorrhiza extracts were mixed, with the best composition ratios being pH 7:pH 1 (3:2 ≈ pH 1.7) and pH 12:pH 13 (1:4 ≈ pH 12.6). The composition of this mixture was applied to the DSSC resulting in an efficiency of 0.096 and 0.147%, respectively.
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来源期刊
Indonesian Journal of Chemistry
Indonesian Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
2.30
自引率
11.10%
发文量
106
审稿时长
15 weeks
期刊介绍: Indonesian Journal of Chemistry is a peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry, including educational chemistry, applied chemistry, and chemical engineering.
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