发泡参数对微波硫化天然胶乳泡沫物性的影响

IF 0.2 Q4 MULTIDISCIPLINARY SCIENCES Suranaree Journal of Science and Technology Pub Date : 2023-10-09 DOI:10.55766/sujst-2023-04-e0873
Tatiya Trongsatitkul, Keavalin Jitkokkruad, Kasama Jarukumjorn, Saowapa Chaiwong
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引用次数: 0

摘要

本文报道了微波硫化与邓禄普法制备天然胶乳泡沫(NRLF)的方法。首先在市售的家用微波炉上对固化步骤的微波加热进行了优化。得到了制备NRLF的工艺窗口和最佳工艺条件。最佳辐照功率为600 W,照射时间为6 min。采用最佳微波硫化工艺,研究了搅拌时间(2、4、6、8、10 min)和发泡速度(650、950、1250、1550、1850 rpm)对NRLFs结构、容重、抗压性能和硬度的影响。一般来说,发泡步骤中搅拌时间和速度的增加都会增加进入胶乳化合物的空气体积。这导致了体积密度和泡沫池数量的增加,但泡沫池尺寸的减小。在950 ~ 1550 rpm的搅拌转速范围内成功制备了NRLF。泡沫速度过低和过高导致乳胶化合物不稳定,不能生产NRLF。随着发泡速度的增加,泡沫细胞结构发生了显著变化。泡沫的力学性能,包括抗压强度和硬度,都与泡沫的容重成线性关系。
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EFFECTS OF FOAMING PARAMETERS ON PHYSICAL PROPERTIES OF MICROWAVE-VULCANIZED NATURAL RUBBER LATEX FOAMS (IVCST2021)
This work reported the use of microwave vulcanization coupled with Dunlop process to prepared natural rubber latex foam (NRLF). Optimization of microwave heating for curing step was firstly carried out using a commercially available domestic microwave oven. The processing window and optimum condition for making NRLF were obtained. The optimum power and time of the irradiation were found at 600 W and 6 min, respectively. Using the optimum microwave vulcanization, effects of stirring time (2, 4, 6, 8, and 10 min) and speed (650, 950, 1250, 1550, and 1850 rpm) of foaming step on cell structure, bulk density, compressive properties, and hardness of NRLFs were investigated. Generally, the increases in the stirring time and speed in foaming step both gave rise to the volume of the air incorporated into the latex compound. This resulted in the increases in the bulk density and the number of cell but, the decrease in foam cell size. The stirring speed in a range of 950 to 1550 rpm was successfully used for preparing the NRLF. Too low and too high foaming speeds caused unstable latex compounds and failed to produce NRLF. The foam cell structure changed dramatically as the foaming speed increased. The foam mechanical properties, both compressive strength and hardness, were found to be linearly related to the foam bulk density.
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来源期刊
Suranaree Journal of Science and Technology
Suranaree Journal of Science and Technology MULTIDISCIPLINARY SCIENCES-
CiteScore
0.30
自引率
50.00%
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0
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