Nitric acid-potassium hydroxide fractionation of rice straw: an integrated biorefinery initiative

Abstract Pulping of rice straw was studied using mild nitric acid in mild conditions. Spent nitric acid was chosen as soil nutrient rather than followed by the liquor recovery. The rice straw was treated with 11.03% nitric acid at 90 °C for 3 h, yielded 53.09% pulp. Nitric acid treated rice straw pulp had high residual lignin and minerals. However, further treatment with 7% potassium hydroxide reduced the residual lignin and produced pulp with kappa number 20.36. The papermaking properties of the nitric acid followed by KOH treated pulp showed better quality than the nitric acid pulp. The spent nitric acid liquor was reused repeatedly, pulp yield decreased and residual lignin content increased in each step of spent nitric acid reusing. The spent nitric acid liquor and potassium hydroxide liquor-mixed together to get a neutral effluent liquor which was rich with potassium, nitrogen and biomass. The nutritional capacity of the effluent liquor was assessed by incubation with control soil. The labile form of organic carbon, nitrogen, potassium phosphorous and iron increased in the incubated soil.