杏核碳吸附剂的化学活化对环境修复中染料的有效去除

C Pub Date : 2023-09-29 DOI:10.3390/c9040093
Vitalii Vashchynskyi, Olena Okhay, Tetiana Boychuk
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引用次数: 0

摘要

以杏核为原料,通过300 ~ 900℃的炭化和不同组分比的KOH化学活化制备碳材料,研究其性能。结果表明,将炭化温度提高到800 ~ 900℃,会导致窄微孔和碳基体的降解。用红外光谱(FTIR)和扫描电镜(SEM)对吸附材料进行了表征,并计算了比表面积。此外,HNO3的额外活化和450°C的退火使表面积增加到1300 m2/g。所得富氮吸附剂对亚甲基蓝和甲基橙的吸附活性分别为190 ~ 235 mg/g和210 ~ 260 mg/g。本研究的结果可以为将来扩大使用杏材料作为低成本吸附剂去除环境修复生产中的染料提供帮助。
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Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO3 and annealing at 450 °C led to an increase in surface area up to 1300 m2/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production.
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