生物炭与芦苇协同修复路基边坡土壤重金属污染的效果研究

Zhangli Jin, Gaopeng Liu
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引用次数: 0

摘要

研究了改性活性炭与植物复合对路基边坡土壤重金属污染的协同修复效果。本研究以小麦壳为原料,氢氧化钾和高锰酸盐为改性剂,水生植物芦苇对路基边坡土壤中的重金属进行修复。考察了吸附剂投加量、吸附剂物理结构参数、不同pH环境和三元复合重金属体实验条件下对重金属Cu、Pb、Cr的吸附量和去除率。实验结果表明,活化后生物炭的总孔容和总比表面积显著增加,分别是活化前的21.4倍和111.7倍。不同吸附剂对重金属离子的去除率依次为Pb >Cr祝辞铜。当吸附剂为生物炭-芦苇联合修复时,对Cu、Pb和Cr的最大吸附量分别为31.25、136和52.3 mg/g。两种吸附剂(生物炭和生物炭芦苇)对Pb的吸附能力最高,对Pb的吸附敏感性高于对Cr和Cu的吸附敏感性。单组分条件下,生物炭对重金属Cu、Pb、Cr的吸附量为Pb >铜比;在三元溶液体系中,生物炭对重金属Cu、Pb、Cr的吸附量为Cu >Cr祝辞Pb。考虑到富营养性物质的吸附能力和去除率,以及吸附剂的使用成本和效果,吸附剂的推荐用量为4-6 g。
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Research on the Effect of Coordinated Remediation of Heavy Metal Pollution in Roadbed Slope Soil by Combining Biochar with Reed
This study investigated the effect of modified activated carbon combined with plants on the coordinated restoration of heavy metal pollution in roadbed slope soil. This study used wheat husks as raw materials, potassium hydroxide and permanganate as modifiers, and aquatic plant reeds to remediate heavy metals in roadbed slope soil. The adsorption amount and removal rate of heavy metals Cu, Pb, and Cr were investigated under adsorbent dosage, adsorbent physical structure parameters, different pH environments, and ternary composite heavy metal body experimental conditions. According to the experimental results, after activation, the total pore volume and total specific surface area of biochar increased significantly, 21.4 and 111.7 times those before activation, respectively. The order of removal rates of heavy metal ions by different adsorbents was Pb > Cr > Cu. When the adsorbent was biochar–reed joint remediation, the maximum adsorption capacity of Cu, Pb, and Cr was 31.25, 136, and 52.3 mg/g. The adsorption capacities of the two adsorbents (biochar and biochar–reed) for Pb were the highest, and the adsorption sensitivity of the adsorbents for Pb was higher than that for Cr and Cu. Under single-component conditions, the adsorption capacity of biochar to heavy metals Cu, Pb, and Cr was ranked as Pb > Cu > Cr. In a ternary solution system, the adsorption capacity of biochar to heavy metals Cu, Pb, and Cr was ranked as Cu > Cr > Pb. Considering the adsorption capacity and removal rate of nutrient-rich substances, as well as the cost and effect of the use of the adsorbent, the recommended amount of the adsorbent was 4–6 g.
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来源期刊
Journal of Biobased Materials and Bioenergy
Journal of Biobased Materials and Bioenergy 工程技术-材料科学:生物材料
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发文量
60
审稿时长
6 months
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