一种简单而通用的液体状涂层策略,适用于各种基材上的各种液体

IF 7.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Cell Reports Physical Science Pub Date : 2023-10-01 DOI:10.1016/j.xcrp.2023.101593
Shouzheng Jiao, Yufen Li, Yang Zhang, Dongjie Zhang, Yuyan Liu, Zhongjun Cheng
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引用次数: 0

摘要

液态聚甲基丙烯酸甲酯(PDMS)刷涂具有较低的液滴附着力,具有重要的基础研究和实际应用价值。共价接枝是制备在大范围表面张力下对各种液体具有低粘附性的PDMS刷的常用策略,但它只适用于高活性无机基底。铸造含有PDMS的混合物可以解决这一问题;但不能保证均匀性和低附着力。在这里,我们报告了一种简单的方法,一步一步喷涂制备PDMS刷,适用于两种基材。具有大范围表面张力的液滴可以以小于10°的滑动角从涂层上滑动。研究结果表明,具有柔性分子链和高功能化的多胺有利于制备具有高接枝密度和良好表面润滑性的毛刷涂层。最后,还展示了良好的稳定性和在耐污、自洁、防爆裂等方面的广泛应用。
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A simple and universal strategy for liquid-like coating suitable for a broad range of liquids on diverse substrates
Liquid-like PDMS brushes coating with low adhesion to droplets are significant in both fundamental research and practical application. Covalent grafting is a common strategy to prepare PDMS brushes with low adhesion to diverse liquids in a wide range of surface tensions, but it is only suitable for high active inorganic substrates. Casting of mixtures containing PDMS can solve this problem; however, homogeneity and low adhesion cannot be guaranteed. Here we report a simple method by step-by-step spraying for preparing PDMS brushes, which is suitable for both substrates. Droplets with a wide range of surface tension can slide off the coating with a sliding angle less than 10°. Research results indicate that the polyamine with flexible molecular chain and high functionality is beneficial for brushes coating with high grafting density and excellent surface lubricity. Finally, good stability and diverse applications in fouling resistance, self-cleaning, anti-bursting, etc. are also demonstrated.
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来源期刊
Cell Reports Physical Science
Cell Reports Physical Science Energy-Energy (all)
CiteScore
11.40
自引率
2.20%
发文量
388
审稿时长
62 days
期刊介绍: Cell Reports Physical Science, a premium open-access journal from Cell Press, features high-quality, cutting-edge research spanning the physical sciences. It serves as an open forum fostering collaboration among physical scientists while championing open science principles. Published works must signify significant advancements in fundamental insight or technological applications within fields such as chemistry, physics, materials science, energy science, engineering, and related interdisciplinary studies. In addition to longer articles, the journal considers impactful short-form reports and short reviews covering recent literature in emerging fields. Continually adapting to the evolving open science landscape, the journal reviews its policies to align with community consensus and best practices.
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