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Coupling of alkynes and aryl halides with nickel-catalyzed Sonogashira reactions 炔和芳卤化合物与镍催化Sonogashira反应的偶联
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-01 DOI: 10.1016/j.xcrp.2023.101573
Hui Chen, Licheng Yao, Lin Guo, Yahu A. Liu, Boxue Tian, Xuebin Liao
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引用次数: 0
Passive radiative cooling to sub-ambient temperatures inside naturally ventilated buildings 在自然通风的建筑物内,被动辐射冷却至低于环境温度
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-01 DOI: 10.1016/j.xcrp.2023.101570
Remy Fortin, Jyotirmoy Mandal, A. Raman, S. Craig
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引用次数: 1
Non-layered dysprosium oxysulfide as an electron-withdrawing chainmail for promoting electrocatalytic oxygen evolution 非层状氧硫化镝作为促进电催化析氧的吸电子链
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-01 DOI: 10.1016/j.xcrp.2023.101571
Xue‐Feng Zhang, Hong-Hong Zou, Li-Weng Ding, Xiao-Xiao Deng, Jia-Jun Zheng, Han-Feng Liu, Zi-Ming Ye, Shengliang Zhong, Ziyan Du, Jia Zhang, Chun-Ting He
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引用次数: 0
Lead-sulfur interaction induced damp and water stability in pure formamidinium lead triiodide. 铅硫相互作用诱导纯甲脒型三碘化铅的湿稳定性和水稳定性。
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-16 DOI: 10.1016/j.xcrp.2023.101516
Muhammed P U Haris, Eliseo Ruiz, Samrana Kazim, Shahzada Ahmad

Research efforts in various multitudes have been demonstrated to stabilize methylammonium (MA)- and bromide (Br)-free formamidinium lead triiodide (FAPI) perovskite thin films. Despite these commendable efforts, pure FAPI perovskite thin film is prone to critical phase-transition issues due to its thermodynamically stable non-perovskite phase (2H). Here, in this work, we propose a rational additivization strategy to overcome this challenge. Our multifunctional ammonium salt containing a sulfur heteroatom shifts the thermodynamic stability from the 2H phase to an intermediate phase closer to the cubic phase. Along with the high crystallinity, micron-sized grains with preferred (00h) facet orientation stem the PbS interaction to offer exceptional stability against high relative humidity, direct water incursion, and shelf-life aging. Our findings through experimental and theoretical studies substantiate the role of PbS interaction in stabilizing the perovskite cubic phase and the stoichiometric distribution of elemental components.

各种各样的研究已经证明了稳定无甲基铵(MA)和溴(Br)的甲脒三碘化铅(FAPI)钙钛矿薄膜的努力。尽管有这些值得称赞的努力,纯FAPI钙钛矿薄膜由于其热力学稳定的非钙钛矿相(2H),容易出现临界相变问题。在这里,在这项工作中,我们提出了一个合理的加和策略来克服这一挑战。我们的含硫杂原子的多功能铵盐将热力学稳定性从2H相转移到更接近立方相的中间相。随着高结晶度,微米尺寸的晶粒具有首选的(00h)面取向阻止Pb…S相互作用,提供卓越的稳定性,抗高相对湿度,直接水侵和货架寿命老化。通过实验和理论研究,我们的发现证实了Pb…S相互作用在稳定钙钛矿立方相和元素组分化学计量分布中的作用。
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引用次数: 1
Origin of rate limitations in solid-state polymer batteries from constrained segmental dynamics within the cathode 固态聚合物电池速率限制的来源:阴极内受限的节段动力学
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-01 DOI: 10.1016/j.xcrp.2023.101538
X. C. Chen, Charles Soulen, Mary K. Burdette-Trofimov, Xiaomin Tang, Changhao Liu, L. Heroux, M. Doucet, M. Tyagi, G. Veith
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引用次数: 0
Ligand “lock and fix” strategy provides stability to metal-organic frameworks for photodegradation processes 配体“锁定和固定”策略为光降解过程的金属有机框架提供稳定性
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-01 DOI: 10.1016/j.xcrp.2023.101545
Fangdi Dong, Xu Wang, Zhiqiang Zhao, Shuai Gao, Guo Wang, Kai Li, Yuqing Lin
{"title":"Ligand “lock and fix” strategy provides stability to metal-organic frameworks for photodegradation processes","authors":"Fangdi Dong, Xu Wang, Zhiqiang Zhao, Shuai Gao, Guo Wang, Kai Li, Yuqing Lin","doi":"10.1016/j.xcrp.2023.101545","DOIUrl":"https://doi.org/10.1016/j.xcrp.2023.101545","url":null,"abstract":"","PeriodicalId":9703,"journal":{"name":"Cell Reports Physical Science","volume":" ","pages":""},"PeriodicalIF":8.9,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45526836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoelectrochemical Si–H and Ge–H activation by iron catalysis 铁催化的光电化学Si–H和Ge–H活化
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-01 DOI: 10.1016/j.xcrp.2023.101550
W. Wei, Simon L Homölle, Tristan von Münchow, Yanjun Li, Isaac Maksso, L. Ackermann
{"title":"Photoelectrochemical Si–H and Ge–H activation by iron catalysis","authors":"W. Wei, Simon L Homölle, Tristan von Münchow, Yanjun Li, Isaac Maksso, L. Ackermann","doi":"10.1016/j.xcrp.2023.101550","DOIUrl":"https://doi.org/10.1016/j.xcrp.2023.101550","url":null,"abstract":"","PeriodicalId":9703,"journal":{"name":"Cell Reports Physical Science","volume":" ","pages":""},"PeriodicalIF":8.9,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44221524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of dipolar molecules on the reliability of organic photovoltaic cells 偶极分子对有机光伏电池可靠性的影响
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-01 DOI: 10.1016/j.xcrp.2023.101551
Xinjing Huang, Yongxi Li, S. Forrest
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引用次数: 0
Rational positioning of 3D-printed voxels to realize high-fidelity multifunctional soft-hard interfaces 三维打印体素的合理定位实现高保真多功能软硬界面
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-01 DOI: 10.1016/j.xcrp.2023.101552
M. C. Saldívar, Shima Salehi, Robin Petrus Elias Veeger, E. Tay, M. Fenu, A. Cantamessa, M. Klimopoulou, G. Talò, M. Moretti, S. Lopa, D. Ruffoni, G. V. van Osch, L. Fratila-Apachitei, Zjenja Doubrovski, M. Mirzaali, A. A. Zadpoor
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引用次数: 0
An N-terminal alpha-synuclein fragment binds lipid vesicles to modulate lipid-induced aggregation 一个n端α -突触核蛋白片段结合脂质囊泡来调节脂质诱导的聚集
IF 8.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-01 DOI: 10.1016/j.xcrp.2023.101563
Richard M. Meade, Scott G. Allen, Christopher Williams, T. Tang, M. Crump, J. Mason
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引用次数: 1
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