非菲[9,10 - d]咪唑:一种意想不到的合成途径

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC Synthesis-Stuttgart Pub Date : 2023-10-05 DOI:10.1055/s-0042-1751493

Stefan F. Kirsch, Bastian L. Springer, Kristina Holzschneider, Fabian Mohr

引用次数: 0

摘要

摘要介绍了一种合成菲[9,10 - d]咪唑的新方法。通过易于获得的10,10-重氮杂菲-9(10H)- 1与亲核胺的氨基水解，引发自缩合，从而形成目标菲[9,10 -d]咪唑。用x射线单晶学研究了材料的分子结构，并描述了材料的光学性质。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Phenanthro[9,10‑d]imidazoles: An Unexpected Synthetic Route

Abstract A new synthetic route for the synthesis of phenanthro[9,10‑d]imidazoles is described. Through aminolysis of easily accessible 10,10-diazidophenanthren-9(10H)-one with nucleophilic amines, a self-condensation is triggered that results in the formation of the target phenanthro[9,10‑d]imidazoles. The molecular structures were studied by X-ray single crystallography, and the optical properties of the material are described.

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来源期刊

Synthesis-Stuttgart 化学-有机化学

CiteScore

4.50

自引率

7.70%

发文量

435

审稿时长

1 months

期刊介绍： SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.