提出了一种利用巯基化学反应制备光滑润滑多孔表面的新方法,用于防污防腐蚀

IF 3.2 3区 化学 Q2 POLYMER SCIENCE e-Polymers Pub Date : 2023-01-01 DOI:10.1515/epoly-2023-0116
Xuezhun Gu, Hao Jiang, Xiaotong Chen, Yu Li, Guoqing Wang
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引用次数: 0

摘要

摘要一种新型的、简单的、高效制备稳定、无毒的滑溜润滑注入多孔表面(SLIPS)的方法将扩大其在海洋环境中的防污和防腐应用。本文通过巯基键合化学反应将端乙烯基聚二甲基硅氧烷共价接枝到纳米二氧化硅表面。然后,在室温下,通过喷涂方法在各种衬底表面上有效地制备了slip。表面润湿性结果表明,10 μL的水滴可以在倾斜10°的表面上滑动,染色后的水滴在滑动过程中可以无污渍地滑动,证明了slip具有良好的滑动性能。粗糙表面存在分子级光滑硅油膜。防污、防腐蚀实验表明,制备的防污、防腐蚀材料在假交替单胞菌培养液中浸泡14天后,具有稳定、优良的防污、防腐蚀性能。该材料对细菌附着的抑制率超过98%,对腐蚀的抑制率达到99.9%。这种简便的方法为在海洋环境中制造防污防腐蚀的slip提供了指导。
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A novel fabrication method of slippery lubricant-infused porous surface by thiol-ene click chemistry reaction for anti-fouling and anti-corrosion applications
Abstract A novel and simple way for efficiently preparing stable and non-toxic slippery lubricant-infused porous surface (SLIPS) will expand its anti-fouling and anti-corrosion applications in marine environments. Herein, vinyl-terminated polydimethylsiloxane was covalently grafted on the surface of nano-SiO 2 by a thiol-ene click chemistry reaction. After that, SLIPS was efficiently prepared at room temperature via the spraying method on various substrate surfaces. Surface wettability results showed that a water droplet (10 μL) can slip on the surface with an inclination of 10° and a stained water droplet can slip without stain during the slide process, which proved that SLIPS displayed excellent slippery performance. The existence of molecular-level slippery silicone oil film on the rough surface. Anti-fouling and anti-corrosion tests showed that the prepared SLIPS exhibited stable and excellent anti-fouling and anti-corrosion performance after immersion in Pseudoalteromonas sp. culture solution for 14 days. The SLIPS exhibited a value of more than 98% of bacterial attachment inhibition efficiency and a value of 99.9% of corrosion inhibition efficiency. This facile method provides guidance to fabricate SLIPS for its anti-fouling and anti-corrosion applications in marine environments.
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来源期刊
e-Polymers
e-Polymers 化学-高分子科学
CiteScore
5.90
自引率
10.80%
发文量
64
审稿时长
6.4 months
期刊介绍: e-Polymers is a strictly peer-reviewed scientific journal. The aim of e-Polymers is to publish pure and applied polymer-science-related original research articles, reviews, and feature articles. It includes synthetic methodologies, characterization, and processing techniques for polymer materials. Reports on interdisciplinary polymer science and on applications of polymers in all areas are welcome. The present Editors-in-Chief would like to thank the authors, the reviewers, the editorial staff, the advisory board, and the supporting organization that made e-Polymers a successful and sustainable scientific journal of the polymer community. The Editors of e-Polymers feel very much engaged to provide best publishing services at the highest possible level.
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