一些天然粘土、酸活性天然粘土、合成吸附剂和金属有机框架对碱性中和葵花籽油漂白能力的研究

Emin YILMAZ, Elif YÜCETEPE
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摘要

本研究的目的是研究30种不同的吸附剂材料的植物油漂白能力,这些材料分为四组(天然粘土、酸活化天然粘土、合成吸附剂、金属有机框架)。对照样品经油处理后,测定了油色(L、a*、b*值)、油失重(%)、游离脂肪酸酸度(FFA)、过氧化值(PV)以及K232和K270的比灭度。在数据分析的基础上,选择了天然蒙脱土、酸活化高岭土、Dowex和Ti-MOF,并对两种商用漂白土(cb.e.)样品进行了相同的测试。最后,将所选的四种吸附剂配制成等量份的混合物,并对其进行吸附实验。结果表明,酸活化的高岭土和Dowex在石油漂白中具有一定的应用潜力。综上所述,其他一些粘土改性技术建议应用于这些潜在的吸附剂,以提高其漂白活性,具有潜在的商业应用价值。
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BAZI NATURAL VE ASİT-AKTİVE NATURAL KİLLERİN, SENTETİK ADSORBANLARIN VE METAL-ORGANİK ÇERÇEVELERİN ALKALİ-NÖTRALİZE AYÇİÇEĞİ YAĞI AĞARTMA YETENEKLERİNİN İNCELENMESİ
The aim of this study was to search vegetable oil bleaching abilities of 30 different adsorbent materials placed into four groups (natural clay, acid-activated natural clay, synthetic adsorbent, metal-organic frames). After oil treatment against control sample, oil color (L, a*, b* values), oil weight loss (%), free fatty acidity (FFA), peroxide value (PV), and the specific extinctions of K232 and K270 were measured. Based on the data analysis, natural montmorillonite, acid-activated halloysite, Dowex, and Ti-MOF were selected, and tested in the same way against two commercial bleaching earth (C.B.E.) samples. Finally, an equal weight portion mixture of the four selected adsorbents were prepared and tested against C.B.Es. Results indicated that acid activated halloysite and Dowex had certain potentials to be implemented in oil bleaching. In conclusion, some other clay modification techniques suggested being applied to those potential adsorbents to improve their bleaching activity for potential commercial applications.
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